WebMO Job Summary

556666: C9H9O2(+1) O-protonated atropic acid anti B3LYP/6-311+G(2d,p), Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C9H9O2(1+)
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -498.784554874 Hartree
ZPE 0.160505 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -498.614525 Hartree
Enthalpy -498.613581 Hartree
Free Energy -498.659574 Hartree
Cv 36.900 cal/mol-K
Entropy 96.800 cal/mol-K
Dipole Moment 6.1652 Debye
Server batch (569729)
CPU time 22246.8 sec

Geometry Sequence Energies

Step Energy  
0 -498.784087695  
1 -498.784505698  
2 -498.784541452  
3 -498.784547461  
4 -498.784553257  
5 -498.784554300  
6 -498.784554702  
7 -498.784554835  
8 -498.784554874  
9 -498.784554874  
10 -498.784554874  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 2.46872 0.08234763531
b 0.71349 0.02379946463
c 0.62794 0.02094582379

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 54.1031 0.7503
2 A 64.3816 4.2832
3 A 101.9762 2.8508
4 A 177.6314 10.1502
5 A 255.3389 18.3763
6 A 337.5740 2.4836
7 A 369.9748 3.5242
8 A 414.0469 0.7338
9 A 451.0197 5.6958
10 A 486.2846 28.2645
11 A 570.1789 294.6943
12 A 593.4214 12.7086
13 A 613.4512 31.5764
14 A 632.5904 2.2556
15 A 658.8623 29.0295
16 A 674.9006 10.0789
17 A 719.0878 66.6108
18 A 747.7351 19.9903
19 A 788.1080 26.3666
20 A 829.1991 38.8101
21 A 866.3212 1.2825
22 A 901.1496 5.9721
23 A 953.9751 3.3959
24 A 999.0101 0.8028
25 A 1017.4563 1.5538
26 A 1020.8930 0.1773
27 A 1047.6986 13.8693
28 A 1052.6754 36.5453
29 A 1106.8859 11.3725
30 A 1118.5637 25.5950
31 A 1176.4551 101.1769
32 A 1185.2074 6.2767
33 A 1208.6989 10.6647
34 A 1224.8683 324.5666
35 A 1288.0565 16.4595
36 A 1315.6135 5.9299
37 A 1367.0842 5.0938
38 A 1442.1112 22.7554
39 A 1477.7794 39.6942
40 A 1515.8759 754.9828
41 A 1530.8547 5.5092
42 A 1575.8262 572.2809
43 A 1611.7334 5.7772
44 A 1635.7950 4.0861
45 A 1659.9373 30.2357
46 A 3165.8467 0.9455
47 A 3170.1600 2.4775
48 A 3175.7638 0.1134
49 A 3183.1447 7.5119
50 A 3190.9799 18.6030
51 A 3198.2115 10.8748
52 A 3260.9132 2.1031
53 A 3583.9260 554.4984
54 A 3684.2571 384.4783
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

IF MATHEMATICALLY YOU END UP WITH THE INCORRECT ANSWER, TRY MULTIPLYING BY THE PAGE NUMBER.