WebMO Job Summary
556782: C8H9ONBr(+1) meta brominated arenium acetanilide in water, Optimize + Vib Freq - Gaussian
Raw Output
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry
C
8
H
9
BrNO(1+)
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-3011.74775384 Hartree
ZPE
0.156793 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-3011.579936 Hartree
Enthalpy
-3011.578992 Hartree
Free Energy
-3011.630243 Hartree
C
v
39.488 cal/mol-K
Entropy
107.865 cal/mol-K
Dipole Moment
9.4943 Debye
Server
batch (569845)
CPU time
7253.1 sec
Geometry Sequence Energies
Step
Energy
0
-3011.74703632
1
-3011.74742250
2
-3011.74766431
3
-3011.74769533
4
-3011.74768833
5
-3011.74772683
6
-3011.74774240
7
-3011.74775149
8
-3011.74775238
9
-3011.74775266
10
-3011.74775287
11
-3011.74775339
12
-3011.74775365
13
-3011.74775384
14
-3011.74775384
15
-3011.74775384
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.39800
0.04663226051
b
0.42300
0.01410976123
c
0.34041
0.01135485536
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
43.2456
13.0659
2
A
46.0727
4.1239
3
A
81.6235
3.1478
4
A
93.0355
1.2408
5
A
115.8928
2.6842
6
A
193.8916
13.2042
7
A
266.3782
1.4724
8
A
287.4546
2.3163
9
A
336.5160
6.7294
10
A
363.7965
1.7418
11
A
411.2108
0.9177
12
A
508.6230
13.4972
13
A
526.8076
43.3124
14
A
568.0384
104.4905
15
A
609.0970
18.0185
16
A
622.4090
23.2023
17
A
651.0287
3.6828
18
A
668.6266
0.7438
19
A
803.9294
39.3456
20
A
834.9571
3.4934
21
A
916.3462
31.2688
22
A
955.1510
18.8697
23
A
960.6079
1.2499
24
A
996.8798
4.7774
25
A
1006.5747
9.1519
26
A
1027.8222
59.4188
27
A
1048.1386
1.0093
28
A
1052.2202
15.7903
29
A
1066.8623
13.3949
30
A
1102.0096
3.4972
31
A
1169.7616
1.7659
32
A
1213.1474
3.9681
33
A
1257.8399
128.3764
34
A
1280.8979
288.2262
35
A
1338.0484
55.6400
36
A
1372.3031
196.3888
37
A
1420.0947
35.0591
38
A
1445.4290
234.6120
39
A
1486.9545
196.1998
40
A
1487.6595
399.1737
41
A
1498.6031
19.0672
42
A
1575.4239
376.2321
43
A
1604.6984
161.3715
44
A
1645.7889
95.8288
45
A
1781.1278
256.2022
46
A
3067.7336
0.9761
47
A
3087.1307
52.7460
48
A
3131.5977
4.9931
49
A
3184.4603
7.3424
50
A
3216.8800
1.4251
51
A
3245.7021
2.4781
52
A
3257.2819
3.7589
53
A
3286.5726
40.1978
54
A
3603.6409
80.8267
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
IT CANNOT BE MY BEAUTY, FOR I HAVE NONE; AND IT CANNOT BE MY WIT, FOR HE HAS NOT ENOUGH TO KNOW THAT I HAVE ANY. -- CATHARINE SEDLEY, PUZZLED ABOUT WHY SHE WAS MISTRESS TO JAMES II