WebMO Job Summary

556798: C6H6NBr 4-bromoaniline Cs in water, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C6H6BrN
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -2858.71473158 Hartree
ZPE 0.107539 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -2858.600069 Hartree
Enthalpy -2858.599125 Hartree
Free Energy -2858.639637 Hartree
Cv 27.192 cal/mol-K
Entropy 85.264 cal/mol-K
Dipole Moment 4.5644 Debye
Server batch (569861)
CPU time 1143.2 sec

Geometry Sequence Energies

Step Energy  
0 -2858.71468010  
1 -2858.71472882  
2 -2858.71473158  
3 -2858.71473158  
4 -2858.71473158  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 5.57670 0.18601868897
b 0.62956 0.02099986118
c 0.56600 0.01887972779

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A' 112.6116 2.2373
2 A" 216.3065 0.2115
3 A' 288.5691 4.0598
4 A' 307.3102 4.5577
5 A" 333.5310 36.1239
6 A" 405.1833 0.4870
7 A" 423.4737 0.1986
8 A' 508.7426 92.7210
9 A' 592.3821 310.1190
10 A' 631.6743 262.1182
11 A" 647.5330 0.0078
12 A' 717.8012 14.6965
13 A" 826.2567 0.1027
14 A' 830.1410 31.3184
15 A' 841.9673 76.9385
16 A" 962.0319 0.0017
17 A' 962.0451 0.2712
18 A' 1013.6593 38.0448
19 A' 1090.1079 27.1430
20 A" 1101.4682 2.9720
21 A" 1161.6658 16.2117
22 A' 1210.3332 26.8869
23 A' 1320.6662 148.3227
24 A" 1337.0079 8.3760
25 A" 1367.0699 3.4830
26 A" 1472.1817 1.9330
27 A' 1538.3359 211.7586
28 A" 1627.7511 1.9513
29 A' 1649.8669 66.3654
30 A' 1689.1747 129.0198
31 A" 3192.4101 13.5224
32 A' 3192.4477 27.0174
33 A" 3220.4091 16.0512
34 A' 3221.6981 0.0510
35 A' 3547.4593 40.4963
36 A" 3642.7970 24.4280
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

SCIENCE SANS CONSCIENCE N'EST QUE RUINE DE L'AME. -- RABELAIS