WebMO Job Summary

556860: CH3N2(+1) protonated diazomethane in ether, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=DiEthylEther) Geom=Connectivity
Stoichiometry CH3N2(1+)
Symmetry C3V
Basis 6-31G(d)
RB3LYP Energy -149.161827196 Hartree
ZPE 0.045365 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -149.112604 Hartree
Enthalpy -149.111660 Hartree
Free Energy -149.139716 Hartree
Cv 10.811 cal/mol-K
Entropy 59.049 cal/mol-K
Dipole Moment 2.3564 Debye
Server batch (569923)
CPU time 358.5 sec

Geometry Sequence Energies

Step Energy  
0 -149.145661562  
1 -149.161636692  
2 -149.161826100  
3 -149.161827181  
4 -149.161827196  
5 -149.161827196  
6 -149.161827196  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 152.07181 5.07256957078
b 9.75055 0.32524333884
c 9.75055 0.32524333884

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 ?A 282.8178 0.3985
2 ?A 284.5660 0.3748
3 ?A 783.9965 1.0807
4 ?A 1140.1290 3.3449
5 ?A 1153.1593 3.1641
6 ?A 1422.0300 14.4098
7 ?A 1445.2510 36.4207
8 ?A 1453.5242 37.3069
9 A1 2488.2018 0.4742
10 ?B 3078.6656 49.8190
11 ?B 3186.6179 41.8483
12 ?B 3193.9284 42.1678
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

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