WebMO Job Summary
556884: C4H6O3 acetoacetic acid in water C1 isomer 1, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry
C
4
H
6
O
3
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-381.728010918 Hartree
ZPE
0.099557 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-381.620688 Hartree
Enthalpy
-381.619744 Hartree
Free Energy
-381.662329 Hartree
C
v
25.772 cal/mol-K
Entropy
89.628 cal/mol-K
Dipole Moment
4.1763 Debye
Server
batch (569947)
CPU time
4201.8 sec
Geometry Sequence Energies
Step
Energy
0
-381.724311983
1
-381.724937381
2
-381.724717934
3
-381.725010840
4
-381.724936882
5
-381.725465292
6
-381.725621260
7
-381.724440267
8
-381.726076142
9
-381.726483533
10
-381.726906632
11
-381.727389627
12
-381.727546743
13
-381.727258867
14
-381.727984375
15
-381.728003299
16
-381.728006910
17
-381.728009212
18
-381.728010504
19
-381.728010852
20
-381.728010918
21
-381.728010918
22
-381.728010918
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.14837
0.17173113808
b
1.64742
0.05495201617
c
1.52058
0.05072108919
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
21.9511
1.6392
2
A
51.8773
7.3594
3
A
125.5056
0.0956
4
A
169.2155
3.2759
5
A
338.0240
4.8184
6
A
400.1179
0.9139
7
A
498.1133
6.3898
8
A
513.9433
27.8322
9
A
559.9495
84.6549
10
A
652.3443
35.0006
11
A
658.9683
134.4154
12
A
814.8815
4.7606
13
A
874.6550
3.5690
14
A
915.2397
4.5386
15
A
1043.5491
10.0741
16
A
1052.0554
41.4468
17
A
1167.1637
375.1864
18
A
1190.2122
16.6653
19
A
1259.8079
24.7316
20
A
1315.9714
39.4981
21
A
1399.7950
199.9352
22
A
1405.9302
54.0479
23
A
1462.3486
30.6746
24
A
1483.4378
23.1433
25
A
1494.6553
23.6134
26
A
1799.2699
285.1203
27
A
1811.8865
402.1241
28
A
3057.6371
1.9871
29
A
3072.8231
1.3451
30
A
3123.1387
5.1577
31
A
3127.4550
2.2128
32
A
3168.5113
15.5806
33
A
3670.1265
92.1690
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
REFRAIN FROM ILLUSIONS, INSIST ON WORK AND NOT WORDS, PATIENTLY SEEK DIVINE AND SCIENTIFIC TRUTH. LAST WORDS OF MARIA MENDELEEVA TO HER SON DMITRI, C. 1850