WebMO Job Summary
556886: C4H6O3 acetoacetic acid in water C1 isomer 3, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry
C
4
H
6
O
3
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-381.733366963 Hartree
ZPE
0.100028 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-381.626007 Hartree
Enthalpy
-381.625062 Hartree
Free Energy
-381.665653 Hartree
C
v
24.964 cal/mol-K
Entropy
85.429 cal/mol-K
Dipole Moment
6.5962 Debye
Server
batch (569949)
CPU time
4069.3 sec
Geometry Sequence Energies
Step
Energy
0
-381.720993979
1
-381.723222461
2
-381.722547918
3
-381.723642878
4
-381.723511027
5
-381.723930305
6
-381.726734405
7
-381.729955070
8
-381.732326804
9
-381.731506876
10
-381.733068231
11
-381.733250688
12
-381.733344382
13
-381.733360710
14
-381.733365638
15
-381.733365737
16
-381.733366134
17
-381.733366457
18
-381.733366830
19
-381.733366960
20
-381.733366963
21
-381.733366963
22
-381.733366963
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.73261
0.19121928678
b
1.72598
0.05757249570
c
1.36313
0.04546912251
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
50.4021
14.1263
2
A
98.0986
3.9564
3
A
128.7059
0.3659
4
A
260.6966
22.2753
5
A
361.9267
10.6418
6
A
403.0010
2.1989
7
A
448.6427
4.5598
8
A
575.6827
25.2722
9
A
578.9417
27.9552
10
A
693.1686
7.6070
11
A
834.0600
88.6442
12
A
853.9316
34.7092
13
A
880.1232
24.3775
14
A
909.1130
6.8474
15
A
999.4147
23.0919
16
A
1061.6147
21.0514
17
A
1199.2755
79.1019
18
A
1231.7284
7.6945
19
A
1278.9130
86.1618
20
A
1369.0684
50.1878
21
A
1414.9756
91.9847
22
A
1439.5902
40.7858
23
A
1470.8325
516.7553
24
A
1478.2380
66.5919
25
A
1488.7694
17.2463
26
A
1757.2120
218.1199
27
A
1835.2416
557.5462
28
A
3042.1020
2.6500
29
A
3058.5596
0.0154
30
A
3119.4992
3.4578
31
A
3132.9325
0.8200
32
A
3174.0620
9.7752
33
A
3278.6102
763.7164
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
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