WebMO Job Summary

556905: C7H14O2 isoamyl acetate, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C7H14O2
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -425.647668731 Hartree
ZPE 0.204268 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -425.431964 Hartree
Enthalpy -425.431020 Hartree
Free Energy -425.481994 Hartree
Cv 39.352 cal/mol-K
Entropy 107.286 cal/mol-K
Dipole Moment 2.0054 Debye
Server batch (569968)
CPU time 4192.1 sec

Geometry Sequence Energies

Step Energy  
0 -425.614081515  
1 -425.643186510  
2 -425.646138409  
3 -425.647500880  
4 -425.647008045  
5 -425.647615890  
6 -425.647667342  
7 -425.647665863  
8 -425.647663954  
9 -425.647668456  
10 -425.647668708  
11 -425.647668717  
12 -425.647668725  
13 -425.647668731  
14 -425.647668733  
15 -425.647668731  
16 -425.647668731  
17 -425.647668731  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.24464 0.14158595010
b 0.59988 0.02000984294
c 0.54922 0.01832000724

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 32.3211 1.7910
2 A 49.1560 0.2836
3 A 59.2642 0.0254
4 A 97.9790 1.2313
5 A 114.5524 0.2765
6 A 185.8082 4.2608
7 A 225.3407 0.8855
8 A 240.7376 3.0371
9 A 248.9497 0.3413
10 A 269.6959 2.4784
11 A 388.8985 0.8579
12 A 399.2226 3.8790
13 A 456.3521 4.3628
14 A 483.8259 3.1352
15 A 603.5046 5.2773
16 A 648.9740 5.4735
17 A 791.2248 0.4834
18 A 829.1764 2.3556
19 A 918.8325 7.7592
20 A 940.8122 1.7796
21 A 963.0074 4.3287
22 A 975.9245 0.1377
23 A 988.1220 4.3650
24 A 1004.5006 0.4605
25 A 1067.6162 80.8286
26 A 1076.3283 7.2029
27 A 1083.5192 51.6628
28 A 1164.4355 3.5142
29 A 1198.4928 4.3472
30 A 1206.4612 4.2161
31 A 1264.2096 32.7370
32 A 1287.0642 429.1466
33 A 1319.8699 8.5043
34 A 1328.2223 0.2330
35 A 1382.4454 2.3353
36 A 1392.9052 3.0579
37 A 1419.6681 50.2900
38 A 1431.4813 4.8932
39 A 1443.4370 6.3029
40 A 1452.1397 5.2011
41 A 1501.1917 12.2704
42 A 1505.7306 7.8221
43 A 1514.3121 0.1661
44 A 1521.1856 1.0296
45 A 1527.9350 1.6417
46 A 1535.8232 3.1026
47 A 1540.5530 8.9619
48 A 1545.3941 5.3094
49 A 1830.3850 229.9022
50 A 3007.2562 15.0748
51 A 3035.0210 9.2061
52 A 3037.6674 34.0682
53 A 3043.9092 25.5510
54 A 3065.9546 20.0784
55 A 3070.6315 4.3500
56 A 3074.5212 12.2187
57 A 3100.7369 5.7754
58 A 3106.6848 58.0931
59 A 3111.3251 33.8753
60 A 3114.4295 61.4736
61 A 3123.6667 36.8195
62 A 3132.5410 7.4113
63 A 3181.9216 8.6932
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

TOWERING GENIUS DISDAINS A BEATEN PATH. IT SEEKS REGIONS HITHERTO UNEXPLORED. -- ABRAHAM LINCOLN