WebMO Job Summary
557182: C7H7N3Cl azide + benzyl chloride SN2 TS, Transition State Optimization & - Gaussian
Raw Output
Save Notes
Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,calcFC) SCRF=(PCM,Solvent=dimethylsulfoxide) Geom=Connectivity FREQ
Stoichiometry
C
7
H
7
ClN
3
(1-)
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-895.471836088 Hartree
ZPE
0.130568 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-895.330636 Hartree
Enthalpy
-895.329692 Hartree
Free Energy
-895.379922 Hartree
C
v
36.767 cal/mol-K
Entropy
105.718 cal/mol-K
Dipole Moment
8.1010 Debye
Server
batch (570245)
CPU time
4540.2 sec
Geometry Sequence Energies
Step
Energy
0
-895.471825937
1
-895.471835974
2
-895.471836148
3
-895.471836088
4
-895.471836088
5
-895.471836088
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
0.92546
0.03087002275
b
0.76393
0.02548196192
c
0.50689
0.01690803042
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
-295.2658
1383.1070
2
A
34.7592
3.8112
3
A
67.1188
0.4645
4
A
75.1150
9.1518
5
A
99.5923
13.5848
6
A
116.6920
24.2084
7
A
147.1997
9.9069
8
A
184.6624
24.6030
9
A
267.8848
60.1082
10
A
368.1097
5.0483
11
A
417.9637
0.2415
12
A
515.6446
67.2926
13
A
535.7951
36.8712
14
A
632.3546
0.3824
15
A
646.3569
21.9741
16
A
659.2811
15.2549
17
A
701.0114
34.7154
18
A
778.8907
19.8760
19
A
832.7129
22.7850
20
A
849.4466
0.9979
21
A
901.6941
0.3534
22
A
928.9545
0.3127
23
A
973.2894
1.1230
24
A
999.5106
2.1124
25
A
1004.7782
0.2313
26
A
1013.6832
14.6724
27
A
1027.8802
164.9299
28
A
1052.8814
1.6531
29
A
1122.8568
4.6713
30
A
1188.5479
0.4813
31
A
1206.7288
4.1727
32
A
1271.5458
98.3600
33
A
1357.3877
1.0965
34
A
1368.8403
3.8329
35
A
1379.3411
8.6922
36
A
1490.7842
15.9015
37
A
1498.5202
17.0094
38
A
1542.6036
3.9366
39
A
1630.1789
0.9943
40
A
1654.0223
22.2599
41
A
2112.1023
1434.9294
42
A
3188.4943
3.0427
43
A
3194.2796
1.2912
44
A
3202.6988
32.0791
45
A
3210.4563
49.8737
46
A
3217.6959
17.7280
47
A
3265.1719
7.8963
48
A
3377.3885
0.1207
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
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