WebMO Job Summary

557191: C7H7Cl benzyl chloride in DMSO Cs, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ SCRF=(PCM,Solvent=dimethylsulfoxide) Geom=Connectivity
Stoichiometry C7H7Cl
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -731.165716288 Hartree
ZPE 0.120141 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -731.038654 Hartree
Enthalpy -731.037710 Hartree
Free Energy -731.078065 Hartree
Cv 25.767 cal/mol-K
Entropy 84.935 cal/mol-K
Dipole Moment 3.1250 Debye
Server batch (570254)
CPU time 820.4 sec

Geometry Sequence Energies

Step Energy  
0 -731.165716288  
1 -731.165716288  
2 -731.165716288  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.15515 0.13860088502
b 0.97107 0.03239140859
c 0.87177 0.02907911713

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A" 51.2482 2.4211
2 A' 109.5372 2.6552
3 A' 270.1550 6.9777
4 A" 332.5780 1.8197
5 A" 415.7062 0.0018
6 A' 476.6198 4.1806
7 A' 559.7415 52.1361
8 A" 633.6678 0.1466
9 A' 637.5374 141.9147
10 A' 711.7066 50.0747
11 A' 783.9263 11.5423
12 A' 825.1021 15.6065
13 A" 862.5510 0.0096
14 A" 922.9967 0.0067
15 A' 939.4320 1.2238
16 A" 978.0840 0.0112
17 A' 1008.2731 0.0498
18 A' 1016.9478 0.6233
19 A' 1055.5692 2.1390
20 A" 1110.9314 8.1601
21 A" 1181.5025 0.0014
22 A" 1189.2964 0.0080
23 A' 1210.1528 0.5290
24 A' 1240.3092 22.1836
25 A' 1305.8621 90.7871
26 A" 1358.2773 0.8928
27 A" 1370.0762 0.9284
28 A" 1500.9551 11.2714
29 A' 1508.9455 2.5717
30 A' 1544.4849 4.9128
31 A" 1641.4744 0.5269
32 A' 1660.0395 1.5234
33 A' 3131.1804 18.1816
34 A' 3186.5271 6.7986
35 A" 3188.4906 4.1680
36 A" 3196.6321 5.8330
37 A' 3197.0746 15.9071
38 A" 3206.2112 53.6888
39 A' 3215.8929 23.9261
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

BETTER TO HUNT IN FIELDS, FOR HEALTH UNBOUGHT THAN FEE THE DOCTOR FOR A NAUSEOUS DRAUGHT. THE WISE, FOR CURE, ON EXERCISE DEPEND; GOD NEVER MADE HIS WORK FOR MAN TO MEND. -- JOHN DRYDEN (1631-1700)