WebMO Job Summary

557321: C7H13(+1) 1-ethylcyclopentylium, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ SCRF=(PCM,Solvent=Water) Geom=Connectivity
Stoichiometry C7H13(1+)
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -274.452508549 Hartree
ZPE 0.182224 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -274.262534 Hartree
Enthalpy -274.261590 Hartree
Free Energy -274.301882 Hartree
Cv 29.568 cal/mol-K
Entropy 84.801 cal/mol-K
Dipole Moment 1.4469 Debye
Server batch (570384)
CPU time 12645.9 sec

Geometry Sequence Energies

Step Energy  
0 -274.424955874  
1 -274.445256060  
2 -274.449869526  
3 -274.449877564  
4 -274.451736939  
5 -274.452281762  
6 -274.452288894  
7 -274.452358678  
8 -274.452503111  
9 -274.452508214  
10 -274.452508549  
11 -274.452508549  
12 -274.452508549  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 5.65864 0.18875191317
b 1.71121 0.05707982153
c 1.39743 0.04661324736

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 95.1605 3.4757
2 A 133.4436 2.1935
3 A 214.6574 1.3275
4 A 231.9292 0.6865
5 A 242.1284 1.5112
6 A 370.6731 8.6355
7 A 430.2895 1.5494
8 A 514.5980 27.7363
9 A 583.9491 2.6311
10 A 638.2509 3.8586
11 A 676.5184 8.9532
12 A 835.9354 36.5523
13 A 864.1034 5.1219
14 A 888.6695 6.0184
15 A 899.0773 2.7730
16 A 933.1246 2.4304
17 A 947.5564 14.7511
18 A 976.4303 13.7646
19 A 993.5653 4.8839
20 A 1020.6078 4.7029
21 A 1051.7246 41.7551
22 A 1124.8368 45.6755
23 A 1156.3012 23.9515
24 A 1186.3980 10.5472
25 A 1215.5592 24.1613
26 A 1233.0599 14.0087
27 A 1255.7165 33.1811
28 A 1286.3032 1.0879
29 A 1296.8446 67.5676
30 A 1323.4723 27.0852
31 A 1340.4439 47.5597
32 A 1359.1134 23.1541
33 A 1365.9387 62.0133
34 A 1376.5194 32.0980
35 A 1401.6420 3.0769
36 A 1426.6271 2.9778
37 A 1454.1882 42.6252
38 A 1496.4210 9.7700
39 A 1497.6059 21.5071
40 A 1498.7842 21.2498
41 A 1505.9080 10.9098
42 A 2910.7494 84.5784
43 A 2919.3524 89.5027
44 A 2931.2594 26.3145
45 A 3040.3037 7.8023
46 A 3048.5213 17.5720
47 A 3057.1397 15.3701
48 A 3063.5083 40.0418
49 A 3087.2354 2.8706
50 A 3099.2966 2.3236
51 A 3113.6867 17.4594
52 A 3121.8167 18.8575
53 A 3122.3879 15.2914
54 A 3127.6143 21.3475
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE GREAT THING ABOUT BEING IMPERFECT IS THE JOY IT BRINGS OTHERS. -- SIGN OUTSIDE LAKE AGASSIZ JR. HIGH SCHOOL, FARGO, N.D.