WebMO Job Summary

557381: C7H13(+1) methylcyclohexylium TS3-4 cis, Transition State Optimization & - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT=(TS,NoEigenTest,calcFC) SCRF=(PCM,Solvent=Water) Geom=Connectivity FREQ
Stoichiometry C7H13(1+)
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -274.432499651 Hartree
ZPE 0.181793 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -274.243789 Hartree
Enthalpy -274.242845 Hartree
Free Energy -274.281200 Hartree
Cv 27.245 cal/mol-K
Entropy 80.725 cal/mol-K
Dipole Moment 6.1165 Debye
Server batch (570444)
CPU time 30663.7 sec

Geometry Sequence Energies

Step Energy  
0 -274.426588162  
1 -274.431755424  
2 -274.431907021  
3 -274.431839898  
4 -274.431914475  
5 -274.432235280  
6 -274.432267071  
7 -274.432410073  
8 -274.432488542  
9 -274.431739916  
10 -274.432317978  
11 -274.432246306  
12 -274.432309698  
13 -274.432380314  
14 -274.432476939  
15 -274.432506732  
16 -274.432505768  
17 -274.432603637  
18 -274.432481044  
19 -274.432458410  
20 -274.432498243  
21 -274.432527030  
22 -274.432504327  
23 -274.432488106  
24 -274.432484191  
25 -274.432499116  
26 -274.432499647  
27 -274.432499588  
28 -274.432499651  
29 -274.432499651  
30 -274.432499651  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.38857 0.14638693813
b 2.25682 0.07527941213
c 1.60937 0.05368280479

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A -178.2910 456.5475
2 A 131.9958 7.6242
3 A 201.6938 0.5056
4 A 240.3473 0.2194
5 A 309.2085 0.6449
6 A 410.4308 5.1198
7 A 427.9134 29.0569
8 A 449.5067 2.4466
9 A 511.3047 3.9221
10 A 670.4892 20.0193
11 A 743.8131 6.0644
12 A 787.2035 2.2172
13 A 864.9243 5.2023
14 A 895.8787 2.3703
15 A 899.3584 4.5599
16 A 952.6307 11.7095
17 A 966.6722 2.4502
18 A 1001.2605 3.9838
19 A 1051.6234 3.2582
20 A 1081.4515 7.9183
21 A 1106.1062 5.9759
22 A 1121.2230 14.7719
23 A 1166.3101 3.7683
24 A 1173.6446 6.9255
25 A 1213.6672 9.6412
26 A 1260.2425 9.6603
27 A 1273.1787 3.0705
28 A 1282.6673 1.4905
29 A 1339.6411 1.3727
30 A 1342.0806 2.8331
31 A 1374.2422 5.6651
32 A 1383.3872 3.1632
33 A 1401.9518 9.5284
34 A 1415.2194 1.3041
35 A 1432.6247 18.9400
36 A 1444.6094 0.2863
37 A 1451.1218 35.6936
38 A 1489.8226 4.8159
39 A 1491.7227 9.1190
40 A 1495.8416 16.2997
41 A 1547.9270 23.5186
42 A 2146.8857 29.7042
43 A 3007.2004 1.7246
44 A 3017.4073 14.7973
45 A 3022.5149 32.3103
46 A 3024.6745 19.8790
47 A 3029.3153 41.3690
48 A 3056.3543 4.3812
49 A 3082.1147 38.6178
50 A 3084.3190 7.7430
51 A 3085.9088 34.7722
52 A 3092.5127 47.1476
53 A 3166.8923 4.4547
54 A 3176.9586 1.3557
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

SCIENCE AT ITS BEST PROVIDES US WITH BETTER QUESTIONS, NOT ABSOLUTE ANSWERS -- NORMAN COUSINS, 1976