WebMO Job Summary

611646: C6H13(+1) secondary cation, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry C6H13(1+)
Symmetry C1
Basis 6-31G(d)
RB3LYP Energy -236.168898308 Hartree
ZPE 0.176118 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -235.984111 Hartree
Enthalpy -235.983167 Hartree
Free Energy -236.025544 Hartree
Cv 30.273 cal/mol-K
Entropy 89.190 cal/mol-K
Dipole Moment 1.2143 Debye
Server batch (624928)
CPU time 3123.8 sec

Geometry Sequence Energies

Step Energy  
0 -236.144075235  
1 -236.161901979  
2 -236.165191036  
3 -236.165920775  
4 -236.165946874  
5 -236.165717329  
6 -236.166408487  
7 -236.167058136  
8 -236.167675954  
9 -236.168617255  
10 -236.168772795  
11 -236.168778016  
12 -236.168882138  
13 -236.168891185  
14 -236.168894786  
15 -236.168896166  
16 -236.168897396  
17 -236.168898165  
18 -236.168898308  
19 -236.168898308  
20 -236.168898308  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 5.65688 0.18869320588
b 2.03424 0.06785494250
c 1.74540 0.05822027718

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 58.2667 2.0414
2 A 90.0021 1.4577
3 A 160.9466 4.9813
4 A 198.4686 0.8543
5 A 216.4860 4.1763
6 A 226.4614 17.7324
7 A 299.4311 7.6220
8 A 334.7146 8.0702
9 A 410.8508 21.7280
10 A 565.1921 12.1901
11 A 654.0042 120.9095
12 A 707.5140 1.1463
13 A 844.1616 26.6241
14 A 886.4502 36.7553
15 A 934.7601 45.1579
16 A 961.3186 3.2363
17 A 968.0593 2.6029
18 A 1036.6440 16.8075
19 A 1065.5675 15.5448
20 A 1078.4047 1.4088
21 A 1121.5323 0.4291
22 A 1183.8093 1.5408
23 A 1202.8863 4.6948
24 A 1222.3411 10.4617
25 A 1302.5485 4.2688
26 A 1337.5212 0.4515
27 A 1386.9028 4.4996
28 A 1414.5560 11.2895
29 A 1440.7380 12.9727
30 A 1449.2833 2.6428
31 A 1458.6172 10.4757
32 A 1482.7637 20.2977
33 A 1501.6577 0.8179
34 A 1504.8233 6.0822
35 A 1520.7124 15.2519
36 A 1524.5951 11.2051
37 A 1530.3770 18.9482
38 A 1550.6969 66.1913
39 A 2883.1357 61.9868
40 A 3072.3031 7.6189
41 A 3074.6787 2.0607
42 A 3077.3271 5.0847
43 A 3108.5229 2.1684
44 A 3121.7438 1.1771
45 A 3148.3877 3.0774
46 A 3152.0950 4.3340
47 A 3155.4092 4.9988
48 A 3157.6212 4.9279
49 A 3159.1608 12.7564
50 A 3168.4090 1.9267
51 A 3193.8673 1.1035
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

FORGIVE MY NONSENSE AS I ALSO FORGIVE THOSE WHO THINK THEY TALK SENSE -- ROBERT FROST