WebMO Job Summary
611647: C6H13(+1) secondary cation isomer 2, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
13
(1+)
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-236.168912657 Hartree
ZPE
0.176738 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-235.983840 Hartree
Enthalpy
-235.982896 Hartree
Free Energy
-236.024241 Hartree
C
v
29.991 cal/mol-K
Entropy
87.018 cal/mol-K
Dipole Moment
2.6756 Debye
Server
batch (624929)
CPU time
5162.3 sec
Geometry Sequence Energies
Step
Energy
0
-236.146095550
1
-236.161315784
2
-236.163637701
3
-236.163362526
4
-236.164800533
5
-236.165597768
6
-236.166524697
7
-236.166853945
8
-236.167064087
9
-236.167181746
10
-236.167210463
11
-236.167218128
12
-236.167265383
13
-236.167322836
14
-236.167372710
15
-236.167370978
16
-236.167528937
17
-236.167404395
18
-236.167748007
19
-236.167389618
20
-236.168023065
21
-236.152701892
22
-236.168702856
23
-236.168467541
24
-236.168756369
25
-236.168853281
26
-236.168525611
27
-236.168902370
28
-236.168908625
29
-236.168909132
30
-236.168909908
31
-236.168911354
32
-236.168912194
33
-236.168912657
34
-236.168912657
35
-236.168912657
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
5.24215
0.17485930216
b
2.23915
0.07469000438
c
1.89181
0.06310398909
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
52.2101
0.1036
2
A
139.6544
13.3711
3
A
184.0043
2.7314
4
A
251.1963
1.4118
5
A
258.9264
0.4142
6
A
275.0652
2.4114
7
A
356.2260
1.1108
8
A
363.3629
5.1330
9
A
414.3676
7.8657
10
A
455.4671
12.9913
11
A
540.3478
99.5216
12
A
808.3429
32.9140
13
A
852.1122
2.8726
14
A
935.7355
9.9551
15
A
948.1141
1.7827
16
A
968.4295
2.8121
17
A
972.2628
0.9593
18
A
1032.9743
1.0090
19
A
1038.4231
99.1750
20
A
1084.9775
12.3619
21
A
1173.8933
1.1994
22
A
1183.7833
1.1833
23
A
1220.4899
15.7783
24
A
1242.8467
0.6316
25
A
1300.9891
6.1352
26
A
1317.3094
2.5349
27
A
1357.7730
13.7657
28
A
1394.6170
41.5877
29
A
1427.3147
19.2107
30
A
1433.0487
29.7803
31
A
1451.4705
1.4234
32
A
1474.1369
28.1731
33
A
1506.0800
0.1692
34
A
1510.3077
6.3424
35
A
1516.9969
21.2336
36
A
1522.2501
9.8169
37
A
1526.7242
11.8459
38
A
1577.9105
29.8859
39
A
2980.5661
20.7053
40
A
2990.8194
43.0429
41
A
3064.0656
4.2203
42
A
3067.1348
0.5047
43
A
3102.3279
2.4715
44
A
3137.7421
6.3398
45
A
3139.2984
1.2474
46
A
3147.4406
2.2159
47
A
3149.2989
2.1623
48
A
3153.1710
8.5841
49
A
3166.9890
0.3992
50
A
3181.5826
3.1230
51
A
3228.3222
1.1363
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
SCIENCE IS LONG AND LIFE IS SHORT. DON MOSER IN THE FEBRUARY 1979 SMITHSONIAN