WebMO Job Summary

61833: C2H6O-Ethanol, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Method B3LYP
Stoichiometry C2H6O
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -155.03379916 Hartree
ZPE 0.080307 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -154.949225 Hartree
Enthalpy -154.948281 Hartree
Free Energy -154.978861 Hartree
Cv 13.382 cal/mol-K
Entropy 64.360 cal/mol-K
Dipole Moment 1.5614 Debye
Server class (62625)
CPU time 42.1 sec

Geometry Sequence Energies

Step Energy (au)  
0 -155.030868775  
1 -155.033684419  
2 -155.033796413  
3 -155.033799160  
4 -155.033799160  
5 -155.033799160  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 34.98182 1.16686791367
b 9.35105 0.31191745324
c 8.13205 0.27125599004

Partial Charges

Atom Symbol Charge
1 C -0.441656  
2 C -0.025725  
3 O -0.613080  
4 H 0.389451  
5 H 0.117849  
6 H 0.117849  
7 H 0.157820  
8 H 0.157820  
9 H 0.139671  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 241.41 (251.4645) 32.5290
2 A" 289.75 (301.8261) 98.8075
3 A' 400.57 (417.2567) 11.2877
4 A" 796.62 (829.8169) 0.0151
5 A' 875.60 (912.0803) 9.8473
6 A' 1001.16 (1042.8794) 55.8699
7 A' 1080.21 (1125.2144) 23.6096
8 A" 1147.20 (1195.0022) 4.8649
9 A' 1240.20 (1291.8762) 86.9236
10 A" 1258.14 (1310.5609) 0.0766
11 A' 1370.70 (1427.8174) 0.4231
12 A' 1422.71 (1481.9939) 16.2672
13 A" 1453.36 (1513.9157) 4.4182
14 A' 1470.52 (1531.7877) 3.0810
15 A' 1498.87 (1561.3249) 2.6943
16 A' 2862.32 (2981.5854) 73.4957
17 A" 2884.62 (3004.8175) 77.9095
18 A' 2935.04 (3057.3366) 15.7327
19 A' 3002.77 (3127.8905) 31.5498
20 A" 3008.13 (3133.4673) 34.3080
21 A' 3600.60 (3750.6252) 9.7374
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

Spring appears, and we are once more children. -- Anonymous