WebMO Job Summary

61837: C2H5O(-1)-Ethoxide, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Method B3LYP
Stoichiometry C2H5O(1-)
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -154.397511624 Hartree
ZPE 0.064141 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -154.329559 Hartree
Enthalpy -154.328615 Hartree
Free Energy -154.358304 Hartree
Cv 11.711 cal/mol-K
Entropy 62.485 cal/mol-K
Dipole Moment 3.1967 Debye
Server class (62629)
CPU time 45.9 sec

Geometry Sequence Energies

Step Energy (au)  
0 -154.384506305  
1 -154.394245844  
2 -154.397089885  
3 -154.397476117  
4 -154.397507894  
5 -154.397511624  
6 -154.397511624  
7 -154.397511624  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 38.31912 1.27818825916
b 9.65825 0.32216454224
c 8.54302 0.28496447366

Partial Charges

Atom Symbol Charge
1 C -0.404569  
2 C 0.151262  
3 O -0.735210  
4 H -0.087199  
5 H -0.087199  
6 H 0.071116  
7 H 0.071116  
8 H 0.020682  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 292.33 (304.5123) 1.3716
2 A' 398.13 (414.7176) 6.6623
3 A" 740.04 (770.8714) 3.8184
4 A' 754.86 (786.3140) 20.0026
5 A' 1008.89 (1050.9281) 36.9174
6 A" 1156.12 (1204.2868) 11.5048
7 A" 1229.19 (1280.4036) 14.1061
8 A' 1230.07 (1281.3259) 115.4978
9 A' 1304.95 (1359.3232) 0.9641
10 A' 1381.05 (1438.5898) 142.6185
11 A" 1432.30 (1491.9784) 0.2643
12 A' 1450.93 (1511.3872) 24.2270
13 A' 1498.43 (1560.8695) 111.9480
14 A" 2193.37 (2284.7607) 712.8214
15 A' 2324.81 (2421.6758) 545.4971
16 A' 2811.07 (2928.1990) 156.7023
17 A' 2898.10 (3018.8517) 123.4775
18 A" 2923.65 (3045.4715) 123.3292
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

The theorems and results in mathematical physics are not theorems and results about Nature, but about our description of it. --Gerard 't Hooft