WebMO Job Summary
623202: C5H8Cl2 dichlorocarbene cis-2-butene adduct TS, Transition State Optimization & - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT=(TS,NoEigenTest,calcFC,tight,MaxStep=2) Geom=Connectivity FREQ int=grid=ultrafine
Stoichiometry
C
5
H
8
Cl
2
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-1115.611646 Hartree
ZPE
0.114261 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-1115.488023 Hartree
Enthalpy
-1115.487078 Hartree
Free Energy
-1115.532951 Hartree
C
v
30.871 cal/mol-K
Entropy
96.548 cal/mol-K
Dipole Moment
2.6743 Debye
Server
batch (636477)
CPU time
8381.2 sec
Geometry Sequence Energies
Step
Energy
0
-1115.61201528
1
-1115.61198738
2
-1115.61195819
3
-1115.61193255
4
-1115.61191030
5
-1115.61189117
6
-1115.61187473
7
-1115.61186045
8
-1115.61184778
9
-1115.61183615
10
-1115.61182508
11
-1115.61181415
12
-1115.61180306
13
-1115.61179162
14
-1115.61177972
15
-1115.61176734
16
-1115.61175452
17
-1115.61174132
18
-1115.61172779
19
-1115.61171401
20
-1115.61170002
21
-1115.61168585
22
-1115.61167153
23
-1115.61165707
24
-1115.61164252
25
-1115.61162789
26
-1115.61161323
27
-1115.61159860
28
-1115.61158412
29
-1115.61156993
30
-1115.61155623
31
-1115.61154326
32
-1115.61153128
33
-1115.61152059
34
-1115.61151152
35
-1115.61150434
36
-1115.61149931
37
-1115.61149663
38
-1115.61149642
39
-1115.61149871
40
-1115.61150353
41
-1115.61151082
42
-1115.61152051
43
-1115.61153245
44
-1115.61154637
45
-1115.61156190
46
-1115.61157857
47
-1115.61159584
48
-1115.61161294
49
-1115.61162846
50
-1115.61164019
51
-1115.61164577
52
-1115.61164604
53
-1115.61164603
54
-1115.61164653
55
-1115.61164601
56
-1115.61164600
57
-1115.61164600
58
-1115.61164600
59
-1115.61164600
60
-1115.61164600
61
-1115.61164600
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.93356
0.06449661919
b
1.15137
0.03840556923
c
1.01268
0.03377936879
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
-101.4498
29.1864
2
A
42.6809
0.1271
3
A
109.5742
1.5608
4
A
120.8461
0.2816
5
A
141.3009
0.4608
6
A
153.0905
0.5214
7
A
203.9633
11.9945
8
A
285.7030
14.2962
9
A
296.4979
0.5568
10
A
317.8158
15.1014
11
A
380.6176
3.5635
12
A
575.2859
9.3632
13
A
636.1445
270.3095
14
A
646.7356
186.4862
15
A
775.3853
30.6669
16
A
875.0431
0.5446
17
A
990.1782
18.7689
18
A
1011.6721
2.2596
19
A
1044.2047
0.3570
20
A
1062.9094
6.4691
21
A
1072.9951
4.3749
22
A
1179.8283
1.3326
23
A
1301.4469
2.6140
24
A
1413.1041
0.0957
25
A
1437.6579
8.5019
26
A
1461.3423
18.6464
27
A
1500.2418
6.7973
28
A
1509.1418
4.2534
29
A
1512.0022
9.3156
30
A
1527.2444
13.4161
31
A
1670.0489
86.0643
32
A
3013.5877
9.2885
33
A
3048.1173
17.6970
34
A
3077.4217
15.6482
35
A
3114.6867
8.2962
36
A
3140.9325
7.7887
37
A
3151.3626
13.6228
38
A
3167.5452
4.3099
39
A
3186.2595
17.5416
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
THE HURRIEDER I GO, THE BEHINDER I GET.