WebMO Job Summary
626070: C6H4O4N2Cl(+1) ortho-nitration of para-chloronitrobenzene, Optimize + Vib Freq - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Stoichiometry
C
6
H
4
ClN
2
O
4
(1+)
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-1101.08758796 Hartree
ZPE
0.105603 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-1100.970463 Hartree
Enthalpy
-1100.969519 Hartree
Free Energy
-1101.021710 Hartree
C
v
40.511 cal/mol-K
Entropy
109.846 cal/mol-K
Dipole Moment
4.7796 Debye
Server
batch (639345)
CPU time
7089.7 sec
Geometry Sequence Energies
Step
Energy
0
-1101.03504709
1
-1101.06907415
2
-1101.07608799
3
-1101.07514730
4
-1101.08189829
5
-1101.08577471
6
-1101.08069017
7
-1101.08240133
8
-1101.08643586
9
-1101.08710861
10
-1101.08730391
11
-1101.08742382
12
-1101.08750538
13
-1101.08755640
14
-1101.08758253
15
-1101.08758764
16
-1101.08758789
17
-1101.08758796
18
-1101.08758796
19
-1101.08758796
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
1.16184
0.03875481084
b
0.47539
0.01585730352
c
0.36292
0.01210570814
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A
38.9002
0.7137
2
A
48.1065
3.0525
3
A
76.0885
18.2387
4
A
84.5706
4.9099
5
A
147.0587
0.8279
6
A
174.4116
94.8807
7
A
199.1739
42.2791
8
A
264.7390
20.9474
9
A
302.7216
0.7522
10
A
304.7595
3.9488
11
A
412.1259
2.5745
12
A
420.5053
54.9009
13
A
470.0582
6.4104
14
A
531.0928
21.3100
15
A
546.1511
18.3011
16
A
605.8302
14.9528
17
A
643.6899
49.8468
18
A
692.9881
151.8847
19
A
723.0932
25.5687
20
A
750.4749
100.4427
21
A
766.7739
138.2569
22
A
850.9787
53.7648
23
A
889.8236
21.5881
24
A
956.6313
10.5923
25
A
988.4174
26.9767
26
A
1040.6311
3.8551
27
A
1058.7695
79.4454
28
A
1088.8262
78.0865
29
A
1114.1093
11.3462
30
A
1134.8263
48.9368
31
A
1182.8053
38.3697
32
A
1305.1829
17.3168
33
A
1348.7344
212.1586
34
A
1373.2580
112.5817
35
A
1384.6239
157.9176
36
A
1409.3392
46.9132
37
A
1490.7761
361.8363
38
A
1551.3952
0.7392
39
A
1643.7566
29.1963
40
A
1701.1390
227.1960
41
A
1813.7111
225.8158
42
A
3111.8046
34.8254
43
A
3232.2229
18.9410
44
A
3237.6154
42.2580
45
A
3241.5910
18.9839
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
BREAD HAS TO MOLD IN ORDER TO GET PENICILLIN. -- JERRY BOATZ