WebMO Job Summary
634727: CH3O2N TS4-4 syn-(aminooxy)methanone (4) Cs N-atom inversion, Ultra_Anharm - Gaussian
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Calculated Quantities
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Overview
Quantity
Value
Route
#N B3LYP/6-311+G(2d,p) OPT=(maxstep=10,maxcycles=50,VeryTight) Geom=Connectivity int=ultrafine FREQ
Stoichiometry
CH
3
NO
2
Symmetry
CS
Basis
6-311+G(2d,p)
RB3LYP Energy
-245.125245194 Hartree
ZPE
0.048877 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-245.072193 Hartree
Enthalpy
-245.071249 Hartree
Free Energy
-245.102621 Hartree
C
v
12.763 cal/mol-K
Entropy
66.029 cal/mol-K
Dipole Moment
2.0078 Debye
Server
default (4203545)
CPU time
423.3 sec
Geometry Sequence Energies
Step
Energy
0
-245.076510501
1
-245.092178217
2
-245.114988736
3
-245.122810979
4
-245.124973728
5
-245.125217548
6
-245.125242189
7
-245.125245135
8
-245.125245193
9
-245.125245194
10
-245.125245194
11
-245.125245194
12
-245.125245194
13
-245.125245194
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
21.42625
0.71470276947
b
7.22291
0.24093034388
c
5.40190
0.18018798859
Vibrational Modes
Mode
Symmetry
Frequency (cm
-1
)
IR (Raman) Intensity
Actions
1
A"
-961.3154
299.6305
2
A"
254.7200
1.0321
3
A'
331.2223
16.0635
4
A"
433.9534
33.9043
5
A'
801.4716
8.4619
6
A'
967.7103
80.6682
7
A"
987.4069
0.5994
8
A'
1194.3780
61.1834
9
A'
1268.9453
39.0175
10
A'
1383.2668
0.8171
11
A'
1514.4725
48.9526
12
A'
1776.8760
353.3037
13
A'
3070.3347
27.0618
14
A'
3625.4823
21.5236
15
A'
3844.4134
120.1562
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
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