WebMO Job Summary

635205: CH3O2N TS9-11, Transition State Optimization - Gaussian

Calculated Quantities

Expand all

Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT=(TS,NoEigenTest,NewEstmFC) Geom=Connectivity freq
Stoichiometry CH3NO2
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -245.02807997 Hartree
ZPE 0.047959 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -244.976135 Hartree
Enthalpy -244.975191 Hartree
Free Energy -245.006208 Hartree
Cv 12.738 cal/mol-K
Entropy 65.281 cal/mol-K
Dipole Moment 6.1760 Debye
Server default (4204268)
CPU time 1051.9 sec

Geometry Sequence Energies

Step Energy  
0 -244.932388431  
1 -244.995845919  
2 -245.021354414  
3 -245.027425010  
4 -245.025925284  
5 -245.026685582  
6 -245.027372197  
7 -245.027703541  
8 -245.027856399  
9 -245.027969533  
10 -245.028008095  
11 -245.028029065  
12 -245.028047702  
13 -245.028064365  
14 -245.028073688  
15 -245.028077748  
16 -245.028079129  
17 -245.028079732  
18 -245.028079970  
19 -245.028079970  
20 -245.028079970  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 17.99210 0.60015185572
b 7.26882 0.24246173665
c 5.70812 0.19040238831

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A -530.2493 75.3830
2 A 317.7703 54.4785
3 A 455.5152 40.2595
4 A 547.1854 118.0756
5 A 687.1217 78.4892
6 A 741.0563 49.1437
7 A 1016.8062 20.3216
8 A 1059.5563 1.5028
9 A 1323.0835 19.6830
10 A 1356.7700 71.7104
11 A 1565.5337 72.0719
12 A 1669.3653 299.5678
13 A 3083.3384 21.8473
14 A 3546.1371 85.0947
15 A 3682.3903 87.0481
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

... FOR AFTERWARDS A MAN FINDS PLEASURE IN HIS PAINS, WHEN HE HAS SUFFERED LONG AND WANDERED FAR. -- HOMER