WebMO Job Summary

635209: CH3O2N TS3-5, Transition State Optimization - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT=(TS,NoEigenTest,NewEstmFC) Geom=Connectivity freq
Stoichiometry CH3NO2
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -245.114726931 Hartree
ZPE 0.048883 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -245.061905 Hartree
Enthalpy -245.060961 Hartree
Free Energy -245.092016 Hartree
Cv 12.140 cal/mol-K
Entropy 65.361 cal/mol-K
Dipole Moment 2.1446 Debye
Server default (4204272)
CPU time 501.4 sec

Geometry Sequence Energies

Step Energy  
0 -245.114687025  
1 -245.114662696  
2 -245.114739425  
3 -245.114722565  
4 -245.114721872  
5 -245.114726570  
6 -245.114726931  
7 -245.114726931  
8 -245.114726931  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 26.18899 0.87357067535
b 5.21172 0.17384426662
c 4.90410 0.16358316793

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A -225.8224 10.2637
2 A 290.6941 9.6638
3 A 381.8485 106.9655
4 A 597.4765 7.0404
5 A 891.3410 35.0522
6 A 927.9430 4.9322
7 A 1038.5932 84.4881
8 A 1096.1375 53.4831
9 A 1329.5175 95.5241
10 A 1397.4758 2.3302
11 A 1470.9563 9.3051
12 A 1838.0462 210.9713
13 A 2938.1184 81.1205
14 A 3456.0482 4.1259
15 A 3803.1050 73.9364
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

Ideas are like rabbits. You get a couple and learn how to handle them, and pretty soon you have a dozen. -- John Steinbeck