WebMO Job Summary

672875: C5H12O UW-Bootcamp tert-amyl alcohol, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-311+G(2d,p) OPT FREQ Geom=Connectivity
Stoichiometry C5H12O
Symmetry C1
Basis 6-311+G(2d,p)
RB3LYP Energy -273.080435972 Hartree
ZPE 0.163351 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -272.908971 Hartree
Enthalpy -272.908026 Hartree
Free Energy -272.948216 Hartree
Cv 29.970 cal/mol-K
Entropy 84.586 cal/mol-K
Dipole Moment 1.5689 Debye
Server batch (686212)
CPU time 6689.8 sec

Geometry Sequence Energies

Step Energy  
0 -273.067190681  
1 -273.079131343  
2 -273.080239877  
3 -273.080406649  
4 -273.080429312  
5 -273.080435435  
6 -273.080435927  
7 -273.080435972  
8 -273.080435972  
9 -273.080435972  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 4.52780 0.15103115102
b 2.58003 0.08606053725
c 2.52067 0.08408050078

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR (Raman) Intensity Actions
1 A 99.6633 1.7628
2 A 212.5418 0.8900
3 A 228.6270 6.2249
4 A 254.3877 24.3636
5 A 257.3143 68.4388
6 A 274.2513 4.2351
7 A 343.0269 3.6282
8 A 367.8370 4.9180
9 A 414.2892 0.4390
10 A 455.0486 7.2603
11 A 521.9587 5.5904
12 A 724.0826 1.6667
13 A 786.3711 0.9850
14 A 881.8196 23.2599
15 A 921.0920 0.2925
16 A 938.8652 23.8630
17 A 1001.4999 0.0668
18 A 1010.5990 5.7825
19 A 1065.8920 30.5134
20 A 1073.5200 4.7594
21 A 1156.2274 31.4883
22 A 1210.8599 40.9699
23 A 1221.9372 11.6778
24 A 1319.6496 2.2713
25 A 1352.7985 24.9310
26 A 1389.0014 15.8798
27 A 1399.2709 14.1204
28 A 1411.8075 6.7572
29 A 1418.8889 5.6911
30 A 1475.9127 0.0602
31 A 1483.7009 0.1274
32 A 1490.1055 2.9957
33 A 1500.8336 10.0938
34 A 1502.3004 3.7380
35 A 1509.6639 12.9049
36 A 1515.0589 1.5794
37 A 3015.9503 10.0195
38 A 3018.4216 31.6250
39 A 3025.4130 37.7865
40 A 3032.6327 21.2414
41 A 3051.4804 10.4470
42 A 3071.9869 2.2471
43 A 3080.1014 62.8546
44 A 3084.4256 34.1078
45 A 3098.1133 26.3601
46 A 3106.6457 36.1728
47 A 3110.3879 18.4891
48 A 3816.6338 15.3166
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

THE MORE ACCURATE THE CALCULATIONS BECOME, THE MORE THE CONCEPTS TEND TO VANISH INTO THIN AIR. -- R.S. MULLIKEN, J.C.P. 43,S2(1965)