WebMO Job Summary
93658: C5H12O 3-methyl-2-butanol, Optimize + Vib Freq - Gaussian
Raw Output
Save Notes
Calculated Quantities
Expand all
Overview
Quantity
Value
Route
#N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Method
B3LYP
Stoichiometry
C
5
H
12
O
Symmetry
C1
Basis
6-31G(d)
RB3LYP Energy
-272.980140332 Hartree
ZPE
0.165488 Hartree
Conditions
298.150K, 1.00000 atm
Internal Energy
-272.806662 Hartree
Enthalpy
-272.805718 Hartree
Free Energy
-272.845928 Hartree
C
v
29.143 cal/mol-K
Entropy
84.629 cal/mol-K
Dipole Moment
1.5992 Debye
Server
class (94418)
CPU time
423 sec
Geometry Sequence Energies
Step
Energy (au)
0
-272.980077923
1
-272.980107156
2
-272.980139173
3
-272.980140173
4
-272.980140248
5
-272.980140332
6
-272.980140332
7
-272.980140332
Animation speed
Loop
None
Loop
Cycle
Rotational Constants
Constant
Frequency (GHz)
Frequency (cm
-1
)
a
4.32939
0.14441290581
b
2.93415
0.09787270899
c
1.90924
0.06368539131
Partial Charges
Atom
Symbol
Charge
1
C
-0.083705
2
C
0.150919
3
O
-0.622122
4
H
0.379880
5
C
-0.452695
6
H
0.144616
7
H
0.141522
8
H
0.145164
9
H
0.104643
10
C
-0.440537
11
H
0.134969
12
H
0.159243
13
H
0.137099
14
C
-0.467029
15
H
0.159035
16
H
0.130131
17
H
0.148688
18
H
0.130180
Vibrational Modes
Show all
Mode
Symmetry
Frequency (cm
-1
)
IR Intensity
Actions
1
A
80.90 (84.2665)
0.7801
2
A
202.14 (210.5641)
0.2136
3
A
215.15 (224.1159)
1.6273
4
A
222.97 (232.2569)
0.1315
5
A
268.53 (279.7152)
4.9060
6
A
293.67 (305.9032)
98.5697
7
A
344.07 (358.4105)
1.5992
8
A
349.21 (363.7628)
10.1497
9
A
393.43 (409.8262)
3.9609
10
A
453.06 (471.9378)
16.4765
11
A
501.42 (522.3119)
4.2378
12
A
753.34 (784.7285)
4.0402
13
A
860.16 (895.9952)
3.6961
14
A
901.20 (938.7531)
4.0742
15
A
912.67 (950.6986)
6.2011
16
A
936.20 (975.2055)
3.7401
17
A
958.89 (998.8445)
10.9609
18
A
1038.03 (1081.2820)
21.3894
19
A
1052.00 (1095.8304)
89.5299
20
A
1110.21 (1156.4682)
6.3720
21
A
1146.00 (1193.7516)
8.4524
22
A
1158.45 (1206.7215)
0.3595
23
A
1237.40 (1288.9594)
6.3976
24
A
1293.03 (1346.9042)
9.0403
25
A
1310.34 (1364.9386)
5.1387
26
A
1348.55 (1404.7412)
0.8272
27
A
1367.54 (1424.5199)
17.0282
28
A
1372.67 (1429.8599)
10.5007
29
A
1378.24 (1435.6704)
24.2753
30
A
1391.24 (1449.2035)
15.9087
31
A
1458.22 (1518.9820)
1.1930
32
A
1459.19 (1519.9902)
0.9900
33
A
1463.06 (1524.0164)
3.3125
34
A
1467.49 (1528.6346)
13.4654
35
A
1475.69 (1537.1758)
1.8910
36
A
1483.82 (1545.6456)
8.3016
37
A
2858.80 (2977.9180)
27.2510
38
A
2913.60 (3035.0004)
12.9823
39
A
2918.46 (3040.0629)
20.7382
40
A
2922.40 (3044.1697)
10.6579
41
A
2929.15 (3051.2015)
54.1472
42
A
2976.06 (3100.0595)
2.6433
43
A
2981.93 (3106.1770)
61.2650
44
A
2985.38 (3109.7717)
47.3563
45
A
2996.78 (3121.6410)
40.9557
46
A
3010.68 (3136.1300)
21.3640
47
A
3017.90 (3143.6414)
21.2986
48
A
3566.09 (3714.6749)
6.4458
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum
Peak Width (cm
-1
)
Quote
LIFE CAN ONLY BE UNDERSTOOD BACKWARD, BUT MUST BE LIVED FORWARD. -- KIRKEGAARD