WebMO Job Summary

93699: C5H11N imine of ethylamine and acetone Cs, Optimize + Vib Freq - Gaussian

Calculated Quantities

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Overview

Quantity Value
Route #N B3LYP/6-31G(d) OPT FREQ Geom=Connectivity
Method B3LYP
Stoichiometry C5H11N
Symmetry CS
Basis 6-31G(d)
RB3LYP Energy -251.899115582 Hartree
ZPE 0.153293 Hartree
Conditions 298.150K, 1.00000 atm
Internal Energy -251.737697 Hartree
Enthalpy -251.736752 Hartree
Free Energy -251.778518 Hartree
Cv 27.708 cal/mol-K
Entropy 87.904 cal/mol-K
Dipole Moment 1.8966 Debye
Server class (94459)
CPU time 157.7 sec

Geometry Sequence Energies

Step Energy (au)  
0 -251.899115195  
1 -251.899115582  
2 -251.899115582  
Animation speed  
Loop  

Rotational Constants

Constant Frequency (GHz) Frequency (cm-1)
a 7.12961 0.23781819088
b 1.96040 0.06539190522
c 1.59854 0.05332155487

Partial Charges

Atom Symbol Charge
1 C -0.502273  
2 C 0.323148  
3 C -0.524850  
4 H 0.170187  
5 H 0.170187  
6 H 0.156154  
7 N -0.398751  
8 C -0.141092  
9 C -0.432162  
10 H 0.130960  
11 H 0.151194  
12 H 0.151194  
13 H 0.132548  
14 H 0.132548  
15 H 0.173555  
16 H 0.153727  
17 H 0.153727  

Vibrational Modes

Mode Symmetry Frequency (cm-1) IR Intensity Actions
1 A" 33.71 (35.1098) 0.4864
2 A" 84.18 (87.6869) 0.3463
3 A" 175.91 (183.2444) 2.1424
4 A' 189.02 (196.9001) 0.4468
5 A" 208.23 (216.9067) 0.1366
6 A" 291.28 (303.4211) 3.5819
7 A' 328.02 (341.6863) 0.6743
8 A' 416.93 (434.3027) 6.1118
9 A" 487.48 (507.7889) 0.8295
10 A' 519.72 (541.3759) 3.3870
11 A" 762.08 (793.8333) 0.6417
12 A' 762.41 (794.1756) 0.2882
13 A' 876.61 (913.1365) 3.7304
14 A" 910.53 (948.4686) 0.0135
15 A' 932.68 (971.5452) 2.6566
16 A' 1000.16 (1041.8327) 7.0876
17 A" 1069.19 (1113.7411) 3.0298
18 A' 1079.71 (1124.6977) 2.4780
19 A' 1091.51 (1136.9899) 0.5111
20 A" 1095.27 (1140.9088) 2.6770
21 A' 1218.29 (1269.0498) 34.2724
22 A" 1265.98 (1318.7289) 0.4719
23 A' 1340.52 (1396.3719) 43.2059
24 A' 1366.27 (1423.1993) 17.5093
25 A' 1371.25 (1428.3831) 2.8346
26 A' 1384.15 (1441.8220) 14.8418
27 A' 1435.13 (1494.9277) 7.8390
28 A' 1442.38 (1502.4751) 12.2472
29 A" 1450.98 (1511.4336) 5.6382
30 A' 1453.26 (1513.8168) 3.4987
31 A" 1454.91 (1515.5316) 7.0232
32 A" 1458.86 (1519.6424) 6.1491
33 A' 1472.27 (1533.6193) 2.8177
34 A' 1674.96 (1744.7498) 103.2208
35 A' 2862.99 (2982.2807) 40.1229
36 A" 2892.09 (3012.5915) 39.3919
37 A' 2912.62 (3033.9782) 20.0154
38 A' 2920.99 (3042.7023) 8.4805
39 A' 2930.54 (3052.6507) 29.7312
40 A" 2959.27 (3082.5741) 20.0676
41 A" 2971.05 (3094.8411) 13.2315
42 A' 2996.24 (3121.0822) 35.4071
43 A" 3003.82 (3128.9770) 33.4584
44 A' 3010.14 (3135.5582) 21.6174
45 A' 3032.95 (3159.3219) 13.1812
Frequency Scale Factor
Normal Mode Amplitude
Animation Speed
IR Spectrum  
Peak Width (cm-1)

Quote

ALL THINGS ARE POSSIBLE EXCEPT SKIING THROUGH A REVOLVING DOOR.