In the right column of the table below,
choose what you feel fits the experimental evidence best--Werner's
theory, Jørgensen's
theory, both, or neither. If an answer is
correct a blue checkmark will appear.
Ionizable Groups
Approximate Conductivities
3
420
2
250
1
100
0
0
We
have decided on the approximate conductivities corresponding to different
numbers of ionizable groups. Now we need to see how well the two
theories predict conductivities which correspond with experiment.
Continue
to choose which theory matches the experimental evidence. Don't be
concerned if the match isn't perfect. For Co(NH3)3(H2O)Cl3,
for instance, the conductivity value is 393 even though only one
ionizable group
is expected. We noticed a color change when this compound dissolved
coupled with an increase in conductivity. We suspect that the original
compound is reacting with water to form a new one with more ionizable
groups.
Good.
You have made the correct choices for all nine metal ammines, I think
this evidence should convince you that my theory is correct. It is
true that aqueous solutions of two compounds, for which I predict
one ionizable groups, have very high conductivities. I think this
occurs because the compounds are reacting with water, forming new
and more ionizable compounds.
We
have decided on the approximate conductivities corresponding to different
numbers of ionizable groups. Now we need to see how well the two
theories predict conductivities which correspond with experiment.
I think
you will see that, in some cases, neither make the correct predictions.
Continue
to choose which theory fits the experimental evidence. You may see
why I think the conductivities are unreliable. for Co(NH3)4Cl3 and
Co(NH3)3(H2O)Cl3 the
conductivities are very high, even though both theories predict only
one ionizable group.
Good.
You have made the correct choices for all nine metal ammines. If
you look closely at the data, I think you will see that the conductivity
evidence is unconvincing. There are two compounds for which neither
of our predictions agree with the conductivities.