Description: Addition of glycerin to a pile of potassium permanganate produces white smoke and a purple flame. The reaction is not instantaneous, but depends on the fineness of the solid crystals.
This demonstration is also available on video and JCE "Chemistry Comes Alive!" vol. 1 CD-Rom.
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Source: Shakhashiri, B.Z. Chemical Demonstrations: A Handbook for Teachers of Chemistry
Year or vol: 1 page 83