Let's look at another example. Thymol blue is another weak acid that is used as an indicator. The fully protonated species (abbreviated H2Thy) is red, the monoprotonated species (HThy-) is yellow, and the fully deprotonated species (Thy2-) is blue. The ionization reactions for thymol blue are shown below:
At any pH, the color of a thymol blue solution can be predicted using the acid ionization constants. For example, at a pH of 4, the [H+] is 1 x 10-4. If this substituted in both acid ionization expressions, two different ratios can be calculated:
This tells you that the concentration of HThy- is 200 times greater than the concentration of H2Thy and over 70,000 times greater than Thy2- (the inverse of 1.3 x 10-5 gives the ratio of HThy- to Thy2-). So HThy- is definately the most prevalent thymol blue species in solution. Since HThy- is yellow, the solution will be yellow. |