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Review Questions Chapter 13

1 Which of the following terms must have a negative sign for a reaction to be spontaneous?

the free energy change
the entropy changel
the enthalpy change
They must all have negative signs
The reaction will be spontaneous only if all these terms are positive.

2. Which of the following statements are always true of a spontaneous reaction?

1. It always occurs rapidly.
2. It is always accompanied by an increase in temperature.
3. It is always exothermic.

none
1 and 2
1 and 3
2 and 3
All are true.

3. Which of the following statements are correct in describing the reaction whose course is shown in the figure?

1. The reaction is endothermic.
2. The addition of a catalyst will raise the activation energy.
3. The reactants have less energy than the products.
4. All the molecules have enough energy to react.

none
2, 3, and 4
1 and 4
1, 2, and 3
all

4. Which of the following changes will increase the rate of the reaction shown in this equation?

4 NH3(g) + 5 O2(g) 4 NO(g) + 6 H2O(g)

1. increasing the concentration of oxygen
2. addition of a catalyst
3. increasing the temperature of the reaction

 

all
none
1
2 and 3
1 and 3

5. Which of the following statements is/are ture of a catalyst?

1. It increase the rate of a reaction
2. It can be recovered unchanged after the reaction ceases.
3. It prevents the reaction from reaching equilibrium.

all
1
2
2 and 3
1 and 2

6. For the equilibrium

2 P(s) + 3H2 2 PH3(g)     H = -9.6 kJ

The equilibrium constant expression is:





none

7. Which of the following will not change the position of the equilibrium shown in Question 6?

increasing the temperature
increasing the pressure
adding a catalyst
increasing the concentration of hydrogen
decreasing the temperature

8. Calculate the concentration of copper(II) ion is a saturated solution of copper(II) sulfide (Ksp of CuS = 8.5x10-45).

2.9x10-23 mol/L
9.2x10-23 mol/L
8.5x10-23 mol/L
2.9x10-23 g/L
not enough data to calculate.

9. Which of the following silver salts is the most soluble?

AgCl, Ksp = 1.5x10-10
AgIO3, Ksp = 9.2x10-9
AgBr, Ksp = 7.7x10-13
AgBrO3, Ksp = 4.0x10-5
AgI, Ksp = 1.0x10-16

10. An acid-base buffer may:

contain a strong acid and the salt of that acid.
resist pH change no matter how much strong acid is added.
contain a weak acid and a salt of that weak acid.
always have a pH of 7.
never be found in biological systems.

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