Department of Chemistry

College of Letters & Science
Ryan MC, Kim YJ, Gerken JB, Wang F, Aristov MM, Martinelli JR, et al.. Mechanistic insights into copper-catalyzed aerobic oxidative coupling of N-N bonds. Chemical Science. 2020;11:1170-1175.
Gerken JB, Stamoulis A, Suh SE, Fischer ND, Kim YJ, Guzei IA, et al.. Efficient electrochemical synthesis of robust, densely functionalized water soluble quinones. Chemical Communications. 2020;56:1199-1202.
Hu HY, Chen SJ, Mandal M, Pratik SM, Buss JA, Krska SW, et al.. Copper-catalysed benzylic C-H coupling with alcohols via radical relay enabled by redox buffering. Nature Catalysis. 2020;.
Li YD, Karlen SD, Demir B, Kim H, Luterbacher J, Dumesic JA, et al.. Mechanistic Study of Diaryl Ether Bond Cleavage during Palladium-Catalyzed Lignin Hydrogenolysis. Chemsuschem. 2020;.
Konnick MM, Knapp SMM, Stahl SS. Mechanism of the reaction of an NHC-coordinated palladium(II)-hydride with O-2 in acetonitrile. Polyhedron. 2020;182.
Preger Y, Johnson MR, Biswas S, Anson CW, Root TW, Stahl SS. Anthraquinone-Mediated Fuel Cell Anode with an Off-Electrode Heterogeneous Catalyst Accessing High Power Density When Paired with a Mediated Cathode. ACS Energy Letters. 2020;5:1407-1412.
Gerken JB, Anson CW, Preger Y, Symons PG, Genders JD, Qiu Y, et al.. Comparison of Quinone-Based Catholytes for Aqueous Redox Flow Batteries and Demonstration of Long-Term Stability with Tetrasubstituted Quinones. Advanced Energy Materials. 2020;10.
Salazar CA, Gair JJ, Flesch KN, Guzei IA, Lewis JC, Stahl SS. Catalytic Behavior of Mono-N-Protected Amino-Acid Ligands in Ligand-Accelerated C-H Activation by Palladium(II). Angewandte Chemie-International Edition. 2020;59:10873-10877.
Salazar CA, Flesch KN, Haines BE, Zhou PS, Musaev DG, Stahl SS. Tailored quinones support high-turnover Pd catalysts for oxidative C-H arylation with O-2. Science. 2020;370:1454-+.
Tereniak SJ, Bruns DL, Stahl SS. Pd-Catalyzed Aerobic Oxidative Coupling of Thiophenes: Synergistic Benefits of Phenanthroline Dione and a Cu Cocatalyst. 2020;142:20318-20323.
Bruns DL, Musaev DG, Stahl SS. Can Donor Ligands Make Pd(OAc)(2) a Stronger Oxidant? Access to Elusive Palladium(II) Reduction Potentials and Effects of Ancillary Ligands via Palladium(II)/Hydroquinone Redox Equilibria. 2020;142:19678-19688.
Wang F, Stahl SS. Electrochemical Oxidation of Organic Molecules at Lower Overpotential: Accessing Broader Functional Group Compatibility with Electron-Proton Transfer Mediators. Accounts of Chemical Research. 2020;53:561-574.
Anson CW, Stahl SS. Mediated Fuel Cells: Soluble Redox Mediators and Their Applications to Electrochemical Reduction of O-2 and Oxidation of H-2, Alcohols, Biomass, and Complex Fuels. Chemical Reviews. 2020;120:3749-3786.
Suh SE, Chen SJ, Mandal M, Guzei IA, Cramer CJ, Stahl SS. Site-Selective Copper-Catalyzed Azidation of Benzylic C-H Bonds. Journal of the American Chemical Society. 2020;142:11388-11393.
Wang F, Gerken JB, Bates DM, Kim YJ, Stahl SS. Electrochemical Strategy for Hydrazine Synthesis: Development and Overpotential Analysis of Methods for Oxidative N-N Coupling of an Ammonia Surrogate. Journal of the American Chemical Society. 2020;142:12349-12356.
Vasilopoulos A, Golden DL, Buss JA, Stahl SS. Copper-Catalyzed C-H Fluorination/Functionalization Sequence Enabling Benzylic C-H Cross Coupling with Diverse Nucleophiles. Organic Letters. 2020;22:5753-5757.
Buss JA, Vasilopoulos A, Golden DL, Stahl SS. Copper-Catalyzed Functionalization of Benzylic C-H Bonds with N-Fluorobenzenesulfonimide: Switch from C-N to C-F Bond Formation Promoted by a Redox Buffer and Bronsted Base. Organic Letters. 2020;22:5749-5752.
Li B, Wendlandt AE, Stahl SS. Replacement of Stoichiometric DDQ with a Low Potential o-Quinone Catalyst Enabling Aerobic Dehydrogenation of Tertiary Indolines in Pharmaceutical Intermediates. Organic Letters. 2019;21:1176-1181.
Perez JM, Kontur WS, Alherech M, Coplien J, Karlen SD, Stahl SS, et al.. Funneling aromatic products of chemically depolymerized lignin into 2-pyrone-4-6-dicarboxylic acid with Novosphingobium aromaticivorans. Green Chemistry. 2019;21:1340-1350.
Wang F, Stahl SS. Merging Photochemistry with Electrochemistry: Functional-Group Tolerant Electrochemical Amination of C(sp(3))-H Bonds. Angewandte Chemie-International Edition. 2019;58:6385-6390.
Wang YH, Schneider PE, Goldsmith ZK, Mondal B, Hammes-Schiffer S, Stahl SS. Bronsted Acid Scaling Relationships Enable Control Over Product Selectivity from O-2 Reduction with a Mononuclear Cobalt Porphyrin Catalyst. ACS Central Science. 2019;5:1024-1034.
Beller M, Shi F, Stahl SS. Preface to Special Issue of ChemSusChem: Sustainable Organic Synthesis. Chemsuschem. 2019;12:2834-2834.
Jaworski JN, Kozack CV, Tereniak SJ, Knapp SMM, Landis CR, Miller JT, et al.. Operando Spectroscopic and Kinetic Characterization of Aerobic Allylic C-H Acetoxylation Catalyzed by Pd(OAc)(2)/4,5-Diazafluoren-9-one. Journal of the American Chemical Society. 2019;141:10462-10474.
Piszel PE, Vasilopoulos A, Stahl SS. Oxidative Amide Coupling from Functionally Diverse Alcohols and Amines Using Aerobic Copper/Nitroxyl Catalysis. Angewandte Chemie-International Edition. 2019;.
Kozack CV, Sowin JA, Jaworski JN, Iosub AV, Stahl SS. Aerobic Acyloxylation of Allylic C-H Bonds Initiated by a Pd-0 Precatalyst with 4,5-Diazafluoren-9-one as an Ancillary Ligand. Chemsuschem. 2019;12:3003-3007.
Ryan MC, Whitmire LD, McCann SD, Stahl SS. Copper/TEMPO Redox Redux: Analysis of PCET Oxidation of TEMPOH by Copper(II) and the Reaction of TEMPO with Copper(I). Inorganic Chemistry. 2019;58:10194-10200.
Das A, Nutting JE, Stahl SS. Electrochemical C-H oxygenation and alcohol dehydrogenation involving Fe-oxo species using water as the oxygen source. Chemical Science. 2019;10:7542-7548.
Singh SK, Savoy AW, Yuan ZY, Luo H, Stahl SS, Hegg EL, et al.. Integrated Two-Stage Alkaline-Oxidative Pretreatment of Hybrid Poplar. Part 1: Impact of Alkaline Pre-Extraction Conditions on Process Performance and Lignin Properties. Industrial & Engineering Chemistry Research. 2019;58:15989-15999.
Rafiee M, Alherech M, Karlen SD, Stahl SS. Electrochemical Aminoxyl-Mediated Oxidation of Primary Alcohols in Lignin to Carboxylic Acids: Polymer Modification and Depolymerization. Journal of the American Chemical Society. 2019;141:15266-15276.
Anson CW, Stahl SS. Processes for Electrochemical Production of Electrolyte-free Hydrogen Peroxide. Joule. 2019;3:2889-2891.
Lennox AJJ, Nutting JE, Stahl SS. Selective electrochemical generation of benzylic radicals enabled by ferrocene-based electron-transfer mediators. Chemical Science. 2018;9:356-361.
Mannel DS, King J, Preger Y, Ahmed MS, Root TW, Stahl SS. Mechanistic Insights into Aerobic Oxidative Methyl Esterification of Primary Alcohols with Heterogeneous PdBiTe Catalystsy. Acs Catalysis. 2018;8:1038-1047.
Das A, Rahimi A, Ulbrich A, Alherech M, Motagamwala AH, Bhalla A, et al.. Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources. Acs Sustainable Chemistry & Engineering. 2018;6:3367-3374.
Wang D, Weinstein AB, White PB, Stahl SS. Ligand-Promoted Palladium-Catalyzed Aerobic Oxidation Reactions. Chemical Reviews. 2018;118:2636-2679.
Nutting JE, Rafiee M, Stahl SS. Tetramethylpiperidine N-Oxyl (TEMPO), Phthalimide N-Oxyl (PINO), and Related N-Oxyl Species: Electrochemical Properties and Their Use in Electrocatalytic Reactions. Chemical Reviews. 2018;118:4834-4885.
Tereniak SJ, Landis CR, Stahl SS. Are Phosphines Viable Ligands for Pd-Catalyzed Aerobic Oxidation Reactions? Contrasting Insights from a Survey of Six Reactions. Acs Catalysis. 2018;8:3708-3714.
Wang F, Rafiee M, Stahl SS. Electrochemical Functional-Group-Tolerant Shono-type Oxidation of Cyclic Carbamates Enabled by Aminoxyl Mediators. Angewandte Chemie-International Edition. 2018;57:6686-6690.
Preger Y, Root TW, Stahl SS. Platinum-Based Heterogeneous Catalysts for Nitrile Synthesis via Aerobic Oxidative Coupling of Alcohols and Ammonia. Acs Omega. 2018;3:6091-6096.
Rafiee M, Konz ZM, Graaf MD, Koolman HF, Stahl SS. Electrochemical Oxidation of Alcohols and Aldehydes to Carboxylic Acids Catalyzed by 4-Acetamido-TEMPO: An Alternative to "Anelli" and "Pinnick" Oxidations. Acs Catalysis. 2018;8:6738-6744.
Gerken JB, Pang YTQ, Lauber MB, Stahl SS. Structural Effects on the pH-Dependent Redox Properties of Organic Nitroxyls: Pourbaix Diagrams for TEMPO, ABNO, and Three TEMPO Analogs. Journal of Organic Chemistry. 2018;83:7323-7330.
Ryan MC, Martinelli JR, Stahl SS. Cu-Catalyzed Aerobic Oxidative N-N Coupling of Carbazoles and Diarylamines Including Selective Cross-Coupling. Journal of the American Chemical Society. 2018;140:9074-9077.
Wang YH, Goldsmith ZK, Schneider PE, Anson CW, Gerken JB, Ghosh S, et al.. Kinetic and Mechanistic Characterization of Low-Overpotential, H2O2-Selective Reduction of O-2 Catalyzed by N2O2-Ligated Cobalt Complexes. Journal of the American Chemical Society. 2018;140:10890-10899.
Lennox AJJ, Goes SL, Webster MP, Koolman HF, Djuric SW, Stahl SS. Electrochemical Aminoxyl-Mediated alpha-Cyanation of Secondary Piperidines for Pharmaceutical Building Block Diversification. Journal of the American Chemical Society. 2018;140:11227-11231.
Rafiee M, Wang F, Hruszkewycz DP, Stahl SS. N-Hydroxyphthalimide-Mediated Electrochemical Iodination of Methylarenes and Comparison to Electron-Transfer-Initiated C-H Functionalization. Journal of the American Chemical Society. 2018;140:22-25.
Mannel DS, Ahmed MS, Root TW, Stahl SS. Discovery of Multicomponent Heterogeneous Catalysts via Admixture Screening: PdBiTe Catalysts for Aerobic Oxidative Esterification of Primary Alcohols. Journal of the American Chemical Society. 2017;139:1690-1698.
Goldsmith ZK, Harshan AK, Gerken JB, Voros M, Galli G, Stahl SS, et al.. Characterization of NiFe oxyhydroxide electrocatalysts by integrated electronic structure calculations and spectroelectrochemistry. Proceedings of the National Academy of Sciences of the United States of America. 2017;114:3050-3055.
Hruszkewycz DP, Miles KC, Thiel OR, Stahl SS. Co/NHPI-mediated aerobic oxygenation of benzylic C-H bonds in pharmaceutically relevant molecules. Chemical Science. 2017;8:1282-1287.
Jaworski JN, McCann SD, Guzei IA, Stahl SS. Detection of Palladium(I) in Aerobic Oxidation Catalysis. Angewandte Chemie-International Edition. 2017;56:3605-3610.
Wang DA, Stahl SS. Pd-Catalyzed Aerobic Oxidative Biaryl Coupling: Non-Redox Cocatalysis by Cu(OTf)(2) and Discovery of Fe(OTf)(3) as a Highly Effective Cocatalyst. Journal of the American Chemical Society. 2017;139:5704-5707.
McCann SD, Lumb JP, Arndtsen BA, Stahl SS. Second-Order Biomimicry: In Situ Oxidative Self-Processing Converts Copper(I)/Diannine Precursor into a Highly Active Aerobic Oxidation Catalyst. Acs Central Science. 2017;3:314-321.
Vasilopoulos A, Zultanski SL, Stahl SS. Feedstocks to Pharmacophores: Cu-Catalyzed Oxidative Arylation of Inexpensive Alkylarenes Enabling Direct Access to Diarylalkanes. Journal of the American Chemical Society. 2017;139:7705-7708.
Das A, Stahl SS. Noncovalent Immobilization of Molecular Electrocatalysts for Chemical Synthesis: Efficient Electrochemical Alcohol Oxidation with a Pyrene-TEMPO Conjugate. Angewandte Chemie-International Edition. 2017;56:8892-8897.
Stahl SS, Rovis T. Cluster Preface: Catalytic Aerobic Oxidations. Synlett. 2017;28:1546-1547.
Ahmed MS, Mannel DS, Root TW, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Carboxylic Acids with a Heterogeneous Pd-Bi-Te/C (PBT/C) Catalyst. Org. Process Res. Dev. 2017;21:1388-1393.
Walroth RC, Miles KC, Lukens JT, MacMillan SN, Stahl SS, Lancaster KM. Electronic Structural Analysis of Copper(II)-TEMPO/ABNO Complexes Provides Evidence for Copper(I)-Oxoammonium Character. Journal of the American Chemical Society. 2017;139:13507-13517.
Wang YH, Pegis ML, Mayer JM, Stahl SS. Molecular Cobalt Catalysts for O-2 Reduction: Low-Overpotential Production of H2O2 and Comparison with Iron-Based Catalysts. Journal of the American Chemical Society. 2017;139:16458-16461.
Anson CW, Stahl SS. Cooperative Electrocatalytic O-2 Reduction Involving Co(salophen) with p-Hydroquinone as an Electron-Proton Transfer Mediator. Journal of the American Chemical Society. 2017;139:18472-18475.
Tereniak SJ, Stahl SS. Mechanistic Basis for Efficient, Site-Selective, Aerobic Catalytic Turnover in Pd-Catalyzed C-H Imidoylation of Heterocycle-Containing Molecules. Journal of the American Chemical Society. 2017;139:14533-14541.
McCann SD, Stahl SS. Mechanism of Copper/Azodicarboxylate-Catalyzed Aerobic Alcohol Oxidation: Evidence for Uncooperative Catalysis. Journal of the American Chemical Society. 2016;138:199-206.
Anson CW, Ghosh S, Hammes-Schiffer S, Stahl SS. Co(salophen)-Catalyzed Aerobic Oxidation of p-Hydroquinone: Mechanism and Implications for Aerobic Oxidation Catalysis. Journal of the American Chemical Society. 2016;138:4186-4193.
White PB, Jaworski JN, Zhu GHarry, Stahl SS. Diazafluorenone-Promoted Oxidation Catalysis: Insights into the Role of Bidentate Ligands in Pd-Catalyzed Aerobic Aza-Wacker Reactions. Acs Catalysis. American Chemical Society; 2016;6:3340-3348.
Shaner SE, Hooker PD, Nickel AM, Leichtfuss AR, Adams CS, de la Cerda D, et al.. Discovering Inexpensive, Effective Catalysts for Solar Energy Conversion: An Authentic Research Laboratory Experience. Journal of Chemical Education. 2016;93:650-657.
Zultanski SL, Zhao JY, Stahl SS. Practical Synthesis of Amides via Copper/ABNO-Catalyzed Aerobic Oxidative Coupling of Alcohols and Amines. Journal of the American Chemical Society. 2016;138:6416-6419.
Badalyan A, Stahl SS. Cooperative electrocatalytic alcohol oxidation with electron-proton-transfer mediators. Nature. 2016;535:406-410.
Miles KC, Abrams ML, Landis CR, Stahl SS. KetoABNO/NOx Cocatalytic Aerobic Oxidation of Aldehydes to Carboxylic Acids and Access to alpha-Chiral Carboxylic Acids via Sequential Asymmetric Hydroformylation/Oxidation. Organic Letters. 2016;18:3590-3593.
Clagg K, Hou HY, Weinstein AB, Russell D, Stahl SS, Koenig SG. Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C-H Bonds. Organic Letters. 2016;18:3586-3589.
Iosub AV, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Cyclic Hydrocarbons for the Synthesis of Substituted Aromatics and Other Unsaturated Products. Acs Catalysis. 2016;6:8201-8213.
Huynh MT, Anson CW, Cavell AC, Stahl SS, Hammes-Schiffer S. Quinone 1 e(-) and 2 e(-)/2 H+ Reduction Potentials: Identification and Analysis of Deviations from Systematic Scaling Relationships. Journal of the American Chemical Society. 2016;138:15903-15910.
White PB, Jaworski JN, Fry CG, Dolinar BS, Guzei IA, Stahl SS. Structurally Diverse Diazafluorene-Ligated Palladium(II) Complexes and Their Implications for Aerobic Oxidation Reactions. Journal of the American Chemical Society. American Chemical Society; 2016;138:4869-4880.
Parajuli R, Gerken JB, Keyshar K, Sullivan I, Sivasankar N, Teamey K, et al.. Integration of Anodic and Cathodic Catalysts of Earth-Abundant Materials for Efficient, Scalable CO2 Reduction. Topics in Catalysis. 2015;58:57-66.
Kim J, Stahl SS. Cu-Catalyzed Aerobic Oxidative Three-Component Coupling Route to N-Sulfonyl Amidines via an Ynamine Intermediate. Journal of Organic Chemistry. 2015;80:2448-2454.
Iosub AV, Stahl SS. Palladium-Catalyzed Aerobic Oxidative Dehydrogenation of Cyclohexenes to Substituted Arene Derivatives. Journal of the American Chemical Society. 2015;137:3454-3457.
Xie XM, Stahl SS. Efficient and Selective Cu/Nitroxyl-Catalyzed Methods for Aerobic Oxidative Lactonization of Diols. Journal of the American Chemical Society. 2015;137:3767-3770.
McCann SD, Stahl SS. Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst. Accounts of Chemical Research. 2015;48:1756-1766.
Pokhrel R, Goetz MK, Shaner SE, Wu XX, Stahl SS. The "Best Catalyst" for Water Oxidation Depends on the Oxidation Method Employed: A Case Study of Manganese Oxides. Journal of the American Chemical Society. 2015;137:8384-8387.
Zheng CW, Stahl SS. Regioselective aerobic oxidative Heck reactions with electronically unbiased alkenes: efficient access to alpha-alkyl vinylarenes. Chemical Communications. 2015;51:12771-12774.
Greene JF, Preger Y, Stahl SS, Root TW. PTFE-Membrane Flow Reactor for Aerobic Oxidation Reactions and Its Application to Alcohol Oxidation. Org. Process Res. Dev. 2015;19:858-864.
Zultanski SL, Stahl SS. Palladium-catalyzed aerobic acetoxylation of benzene using NOx-based redox mediators. Journal of Organometallic Chemistry. 2015;793:263-268.
Iosub AV, Stahl SS. Catalytic Aerobic Dehydrogenation of Nitrogen Heterocycles Using Heterogeneous Cobalt Oxide Supported on Nitrogen-Doped Carbon. Organic Letters. 2015;17:4404-4407.
Steves JE, Stahl SS. Stable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl-Catalyzed Aerobic Alcohol Oxidation. Journal of Organic Chemistry. 2015;80:11184-11188.
Rafiee M, Miles KC, Stahl SS. Electrocatalytic Alcohol Oxidation with TEMPO and Bicyclic Nitroxyl Derivatives: Driving Force Trumps Steric Effects. Journal of the American Chemical Society. 2015;137:14751-14757.
Steves JE, Preger Y, Martinelli JR, Welch CJ, Root TW, Hawkins JM, et al.. Process Development of CuI/ABNO/NMI-Catalyzed Aerobic Alcohol Oxidation. Org. Process Res. Dev. 2015;19:1548-1553.
Osterberg PM, Niemeier JK, Welch CJ, Hawkins JM, Martinelli JR, Johnson TE, et al.. Experimental Limiting Oxygen Concentrations for Nine Organic Solvents at Temperatures and Pressures Relevant to Aerobic Oxidations in the Pharmaceutical Industry. Org. Process Res. Dev. 2015;19:1537-1543.
Chen JYC, Dang LN, Liang HF, Bi WL, Gerken JB, Jin S, et al.. Operando Analysis of NiFe and Fe Oxyhydroxide Electrocatalysts for Water Oxidation: Detection of Fe4+ by Mossbauer Spectroscopy. Journal of the American Chemical Society. 2015;137:15090-15093.
Wendlandt AE, Stahl SS. Quinone-Catalyzed Selective Oxidation of Organic Molecules. Angewandte Chemie-International Edition. 2015;54:14638-14658.
Tsybizova A, Ryland BL, Tsierkezos N, Stahl SS, Roithova J, Schroder D. Speciation Behavior of Copper( II) Acetate in Simple Organic Solvents - Revealing the Effect of Trace Water. European Journal of Inorganic Chemistry. 2014;2014:1407-1412.
Stephenson NA, Gellman SH, Stahl SS. Ammonolysis of anilides promoted by ethylene glycol and phosphoric acid. Rsc Advances. 2014;4:46840-46843.
Wendlandt AE, Stahl SS. Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions. Journal of the American Chemical Society. 2014;136:11910-11913.
Ryland BL, McCann SD, Brunold TC, Stahl SS. Mechanism of Alcohol Oxidation Mediated by Copper(II) and Nitroxyl Radicals. Journal of the American Chemical Society. 2014;136:12166-12173.
Weinstein AB, Stahl SS. Palladium catalyzed aryl C-H amination with O-2 via in situ formation of peroxide-based oxidant(s) from dioxane. Catalysis Science & Technology. 2014;4:4301-4307.
Diao TN, Stahl SS. O-2-promoted allylic acetoxylation of alkenes: Assessment of "push" versus "pull" mechanisms and comparison between O-2 and benzoquinone. Polyhedron. 2014;84:96-102.
Wendlandt AE, Stahl SS. Bioinspired Aerobic Oxidation of Secondary Amines and Nitrogen Heterocycles with a Bifunctional Quinone Catalyst. Journal of the American Chemical Society. 2014;136:506-512.
Chen JYC, Miller JT, Gerken JB, Stahl SS. Inverse spinel NiFeAlO4 as a highly active oxygen evolution electrocatalyst: promotion of activity by a redox-inert metal ion. Energy & Environmental Science. 2014;7:1382-1386.
Gerken JB, Shaner SE, Masse RC, Porubsky NJ, Stahl SS. A survey of diverse earth abundant oxygen evolution electrocatalysts showing enhanced activity from Ni-Fe oxides containing a third metal. Energy & Environmental Science. 2014;7:2376-2382.
Wang D, Izawa Y, Stahl SS. Pd-Catalyzed Aerobic Oxidative Coupling of Arenes: Evidence for Transmetalation between Two Pd(II)-Aryl Intermediates. Journal of the American Chemical Society. 2014;136:9914-9917.
Ryland BL, Stahl SS. Practical Aerobic Oxidations of Alcohols and Amines with Homogeneous Copper/TEMPO and Related Catalyst Systems. Angewandte Chemie-International Edition. 2014;53:8824-8838.
Rahimi A, Ulbrich A, Coon JJ, Stahl SS. Formic-acid-induced depolymerization of oxidized lignin to aromatics. Nature. 2014;515:249-52.
Gladysz JA, Bedford RB, Fujita M, Gabbai FP, Goldberg KI, Holland PL, et al.. Organometallics Roundtable 2013-2014. Organometallics. 2014;33:1505-1527.
Ye X, White PB, Stahl SS. Mechanistic Studies of Wacker-Type Amidocyclization of Alkenes Catalyzed by (IMes)Pd(TFA)(2)(H2O): Kinetic and Stereochemical Implications of Proton Transfer. Journal of Organic Chemistry. 2013;78:2083-2090.
Weinstein AB, Schuman DP, Tan ZX, Stahl SS. Synthesis of Vicinal Aminoalcohols by Stereoselective Aza-Wacker Cyclizations: Access to (-)-Acosamine by Redox Relay. Angewandte Chemie-International Edition. 2013;52:11867-11870.
Suess AM, Ertem MZ, Cramer CJ, Stahl SS. Divergence between Organometallic and Single-Electron-Transfer Mechanisms in Copper(II)-Mediated Aerobic C-H Oxidation. Journal of the American Chemical Society. 2013;135:9797-9804.
Steves JE, Stahl SS. Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems. Journal of the American Chemical Society. 2013;135:15742-15745.
Rahimi A, Azarpira A, Kim H, Ralph J, Stahl SS. Chemoselective Metal-Free Aerobic Alcohol Oxidation in Lignin. Journal of the American Chemical Society. 2013;135:6415-6418.
Pun D, Diao TN, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Phenol Catalyzed by Pd(TFA)(2)/2-Dimethylaminopyridine: Evidence for the Role of Pd Nanoparticles. Journal of the American Chemical Society. 2013;135:8213-8221.
Powell AB, Stahl SS. Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst. Organic Letters. 2013;15:5072-5075.
Martinez C, Wu YC, Weinstein AB, Stahl SS, Liu GS, Muniz K. Palladium-Catalyzed Intermolecular Aminoacetoxylation of Alkenes and the Influence of Phl(OAc)(2) on Aminopalladation Stereoselectivity. Journal of Organic Chemistry. 2013;78:6309-6315.
Lauber MB, Stahl SS. Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System. Acs Catalysis. 2013;3:2612-2616.
Kim J, Stahl SS. Cu/Nitroxyl-Catalyzed Aerobic Oxidation of Primary Amines into Nitriles at Room Temperature. Acs Catalysis. 2013;3:1652-1656.
Izawa Y, Zheng CW, Stahl SS. Aerobic Oxidative Heck/Dehydrogenation Reactions of Cyclohexenones: Efficient Access to meta-Substituted Phenols. Angewandte Chemie-International Edition. 2013;52:3672-3675.
Hoover JM, Ryland BL, Stahl SS, I JOf The Che. Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems. Acs Catalysis. 2013;3:2599-2605.
Hoover JM, Ryland BL, Stahl SS. Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation. Journal of the American Chemical Society. 2013;135:2357-2367.
Hong WP, Iosub AV, Stahl SS. Pd-Catalyzed Semmler-Wolff Reactions for the Conversion of Substituted Cyclohexenone Oximes to Primary Anilines. Journal of the American Chemical Society. 2013;135:13664-13667.
Hill NJ, Hoover JM, Stahl SS. Aerobic Alcohol Oxidation Using a Copper(I)/TEMPO Catalyst System: A Green, Catalytic Oxidation Reaction for the Undergraduate Organic Chemistry Laboratory. Journal of Chemical Education. 2013;90:102-105.
Greene JF, Hoover JM, Mannel DS, Root TW, Stahl SS. Continuous-Flow Aerobic Oxidation of Primary Alcohols with a Copper(I)/TEMPO Catalyst. Org. Process Res. Dev. 2013;17:1247-1251.
Gerken JB, Rigsby ML, Ruther RE, Perez-Rodriguez RJ, Guzei IA, Hamers RJ, et al.. Modular Synthesis of Alkyne-Substituted Ruthenium Polypyridyl Complexes Suitable for "Click" Coupling. Inorganic Chemistry. 2013;52:2796-2798.
Diao TN, Pun D, Stahl SS. Aerobic Dehydrogenation of Cyclohexanone to Cyclohexenone Catalyzed by Pd(DMSO)(2)(TFA)(2): Evidence for Ligand-Controlled Chemoselectivity. Journal of the American Chemical Society. 2013;135:8205-8212.
Hoover JM, Stahl SS. Air oxidation of primary alcohols catalyzed by copper(I)/TEMPO. Preparation of 2-amino-5-bromobenzaldehyde. Organic Syntheses. 2013;90:240-250.
Zheng CW, Wang D, Stahl SS. Catalyst-Controlled Regioselectivity in the Synthesis of Branched Conjugated Dienes via Aerobic Oxidative Heck Reactions. Journal of the American Chemical Society. 2012;134:16496-16499.
Zhang JH, Markiewicz MJ, Weisblum B, Stahl SS, Gellman SH. Functionally Diverse Nylon-3 Copolymers from Readily Accessible beta-Lactams. Acs Macro Letters. 2012;1:714-717.
Zhang J, Markiewicz MJ, Mowery BP, Weisblurn B, Stahl SS, Gellman SH. C-Terminal Functionalization of Nylon-3 Polymers: Effects of C-Terminal Groups on Antibacterial and Hemolytic Activities. Biomacromolecules. 2012;13:323-331.
Wendlandt AE, Stahl SS. Copper(II)-mediated oxidative cyclization of enamides to oxazoles. Organic & Biomolecular Chemistry. 2012;10:3866-3870.
Rigsby ML, Mandal S, Nam W, Spencer LC, Llobet A, Stahl SS. Cobalt analogs of Ru-based water oxidation catalysts: overcoming thermodynamic instability and kinetic lability to achieve electrocatalytic O-2 evolution. Chemical Science. 2012;3:3058-3062.
King AE, Ryland BL, Brunold TC, Stahl SS. Kinetic and Spectroscopic Studies of Aerobic Copper(II)-Catalyzed Methoxylation of Arylboronic Esters and Insights into Aryl Transmetalation to Copper(II). Organometallics. 2012;31:7948-7957.
Gerken JB, Chen JYC, Masse RC, Powell AB, Stahl SS. Development of an O-2-Sensitive Fluorescence-Quenching Assay for the Combinatorial Discovery of Electrocatalysts for Water Oxidation. Angewandte Chemie-International Edition. 2012;51:6676-6680.
Diao TN, White P, Guzei IA, Stahl SS. Characterization of DMSO Coordination to Palladium(II) in Solution and Insights into the Aerobic Oxidation Catalyst, Pd(DMSO)(2)(TFA)(2). Inorganic Chemistry. 2012;51:11898-11909.
Diao T, Wadzinski TJ, Stahl SS. Direct aerobic alpha,beta-dehydrogenation of aldehydes and ketones with a Pd (TFA)(2)/4,5-diazafluorenone catalyst. Chemical Science. 2012;3:887-891.
Campbell AN, Stahl SS. Overcoming the "Oxidant Problem": Strategies to Use O-2 as the Oxidant in Organometallic C-H Oxidation Reactions Catalyzed by Pd (and Cu). Accounts of Chemical Research. 2012;45:851-863.
Wendlandt AE, Stahl SS. Chemoselective Organocatalytic Aerobic Oxidation of Primary Amines to Secondary Imines. Organic Letters. 2012;14:2850-2853.
Redford JE, McDonald RI, Rigsby ML, Wiensch JD, Stahl SS. Stereoselective Synthesis of cis-2,5-Disubstituted Pyrrolidines via Wacker-Type Aerobic Oxidative Cyclization of Alkenes with tert-Butanesulfinamide Nucleophiles. Organic Letters. 2012;14:1242-1245.
Lu Z, Stahl SS. Intramolecular Pd(II)-Catalyzed Aerobic Oxidative Amination of Alkenes: Synthesis of Six-Membered N-Heterocycles. Organic Letters. 2012;14:1234-1237.
Weinstein AB, Stahl SS. Reconciling the Stereochemical Course of Nucleopalladation with the Development of Enantioselective Wacker-Type Cyclizations. Angew. Chem., Int. Ed. 2012;51:11505-11509.
Hoover JM, Steves JE, Stahl SS. Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air. Nature Protocols. 2012;7:1161-1166.
Ye X, Liu G, Popp BV, Stahl SS. Mechanistic Studies of Wacker-Type Intramolecular Aerobic Oxidative Amination of Alkenes Catalyzed by Pd(OAc)(2)/Pyridine. Journal of Organic Chemistry. 2011;76:1031-1044.
Ruther RE, Rigsby ML, Gerken JB, Hogendoorn SR, Landis EC, Stahl SS, et al.. Highly Stable Redox-Active Molecular Layers by Covalent Grafting to Conductive Diamond. Journal of the American Chemical Society. 2011;133:5692-5694.
McDonald RI, White PB, Weinstein AB, Tam CP, Stahl SS. Enantioselective Pd(II)-Catalyzed Aerobic Oxidative Amidation of Alkenes and Insights into the Role of Electronic Asymmetry in Pyridine-Oxazoline Ligands. Organic Letters. 2011;13:2830-2833.
McDonald RI, Liu G, Stahl SS. Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications. Chemical Reviews. 2011;111:2981-3019.
Konnick MM, Decharin N, Popp BV, Stahl SS. O-2 insertion into a palladium(II)-hydride bond: Observation of mechanistic crossover between HX-reductive-elimination and hydrogen-atom-abstraction pathways. Chemical Science. 2011;2:326-330.
Izawa Y, Pun D, Stahl SS. Palladium-Catalyzed Aerobic Dehydrogenation of Substituted Cyclohexanones to Phenols. Science. 2011;333:209-213.
Huffman LM, Stahl SS. Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex. Dalton Transactions. 2011;40:8959-8963.
Hoover JM, Stahl SS. Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols. Journal of the American Chemical Society. 2011;133:16901-16910.
Gerken JB, McAlpin GJ, Chen JYC, Rigsby ML, Casey WH, Britt DR, et al.. Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0-14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity. Journal of the American Chemical Society. 2011;133:14431-14442.
Diao T, Stahl SS. Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones. Journal of the American Chemical Society. 2011;133:14566-14569.
Decharin N, Stahl SS. Benzoquinone-Promoted Reaction of O-2 with a Pd-II-Hydride. Journal of the American Chemical Society. 2011;133:5732-5735.
Decharin N, Popp BV, Stahl SS. Reaction of O(2) with [(-)-Sparteine]Pd(H)Cl: Evidence for an Intramolecular [H-L](+) "Reductive Elimination" Pathway. Journal of the American Chemical Society. 2011;133:13268-13271.
Campbell AN, Meyer EB, Stahl SS. Regiocontrolled aerobic oxidative coupling of indoles and benzene using Pd catalysts with 4,5-diazafluorene ligands. Chemical Communications. 2011;47:10257-10259.
Benson MC, Ruther RE, Gerken JB, Rigsby ML, Bishop LM, Tan Y, et al.. Modular "Click" Chemistry for Electrochemically and Photoelectrochemically Active Molecular Interfaces to Tin Oxide Surfaces. ACS Applied Materials & Interfaces. 2011;3:3110-3119.
White PB, Stahl SS. Reversible Alkene Insertion into the Pd-N Bond of Pd(II)-Sulfonamidates and Implications for Catalytic Amidation Reactions. Journal of the American Chemical Society. 2011;133:18594-18597.
Huffman LM, Casitas A, Font M, Canta M, Costas M, Ribas X, et al.. Observation and Mechanistic Study of Facile C-O Bond Formation between a Well-Defined Aryl-Copper(III) Complex and Oxygen Nucleophiles. Chem. - Eur. J. 2011;17:10643-10650, S10643/1-S10643/48.
Wendlandt AE, Suess AM, Stahl SS. Copper-Catalyzed Aerobic Oxidative C-H Functionalizations: Trends and Mechanistic Insights. Angewandte Chemie-International Edition. 2011;50:11062-11087.
Stahl SS. Organotransition Metal Chemistry: From Bonding to Catalysis by John Hartwig. 2010. pp. 8524-8525.
Zhang J, Gellman SH, Stahl SS. Kinetics of Anionic Ring-Opening Polymerization of Variously Substituted beta-Lactams: Homopolymerization and Copolymerization. Macromolecules. 2010;43:5618-5626.
Ye X, Johnson MD, Diao T, Yates MH, Stahl SS. Development of safe and scalable continuous-flow methods for palladium-catalyzed aerobic oxidation reactions. Green Chemistry. 2010;12:1180-1186.
Popp BV, Morales CM, Landis CR, Stahl SS. Electronic Structural Comparison of the Reactions of Dioxygen and Alkenes with Nitrogen-Chelated Palladium(0). Inorganic Chemistry. 2010;49:8200-8207.
McDonald RI, Wong GW, Neupane RP, Stahl SS, Landis CR. Enantioselective Hydroformylation of N-Vinyl Carboxamides, Allyl Carbamates, and Allyl Ethers Using Chiral Diazaphospholane Ligands. Journal of the American Chemical Society. 2010;132:14027-14029.
McDonald RI, Stahl SS. Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides. Angewandte Chemie-International Edition. 2010;49:5529-5532.
King AE, Huffman LM, Casitas A, Costas M, Ribas X, Stahl SS. Copper-Catalyzed Aerobic Oxidative Functionalization of an Arene C-H Bond: Evidence for an Aryl-Copper(III) Intermediate. Journal of the American Chemical Society. 2010;132:12068-12073.
Izawa Y, Stahl SS. Aerobic Oxidative Coupling of o-Xylene: Discovery of 2-Fluoropyridine as a Ligand to Support Selective Pd-Catalyzed C-H Functionalization. Advanced Synthesis & Catalysis. 2010;352:3223-3229.
Gerken JB, Landis EC, Hamers RJ, Stahl SS. Fluoride-Modulated Cobalt Catalysts for Electrochemical Oxidation of Water under Non-Alkaline Conditions. Chemsuschem. 2010;3:1176-1179.
Dohm MT, Mowery BP, Czyzewski AM, Stahl SS, Gellman SH, Barron AE. Biophysical Mimicry of Lung Surfactant Protein B by Random Nylon-3 Copolymers. Journal of the American Chemical Society. 2010;132:7957-7967.
Casitas A, Poater A, Sola M, Stahl SS, Costas M, Ribas X. Molecular mechanism of acid-triggered aryl-halide reductive elimination in well-defined aryl-Cu-III-halide species. Dalton Transactions. 2010;39:10458-10463.
Casitas A, King AE, Parella T, Costas M, Stahl SS, Ribas X. Direct observation of Cu-I/Cu-III redox steps relevant to Ullmann-type coupling reactions. Chemical Science. 2010;1:326-330.
Campbell AN, White PB, Guzei IA, Stahl SS. Allylic C-H Acetoxylation with a 4,5-Diazafluorenone-Ligated Palladium Catalyst: A Ligand-Based Strategy To Achieve Aerobic Catalytic Turnover. Journal of the American Chemical Society. 2010;132:15116-15119.
Zhang JH, Kissounko DA, Lee SE, Gellman SH, Stahl SS. Access to Poly-beta-Peptides with Functionalized Side Chains and End Groups via Controlled Ring-Opening Polymerization of beta-Lactams. Journal of the American Chemical Society. 2009;131:1589-1597.
Yang LJ, Lu Z, Stahl SS. Regioselective copper-catalyzed chlorination and bromination of arenes with O-2 as the oxidant. Chemical Communications. 2009;:6460-6462.
Stephenson NA, Zhu J, Gellman SH, Stahl SS. Catalytic Transamidation Reactions Compatible with Tertiary Amide Metathesis under Ambient Conditions. Journal of the American Chemical Society. 2009;131:10003-10008.
Scarborough CC, McDonald RI, Hartmann C, Sazama GT, Bergant A, Stahl SS. Steric Modulation of Chiral Biaryl Diamines via Pd-Catalyzed Directed C-H Arylation. Journal of Organic Chemistry. 2009;74:2613-2615.
Scarborough CC, Bergant A, Sazama GT, Guzei IA, Spencer LC, Stahl SS. Synthesis of Pd-II complexes bearing an enantiomerically resolved seven-membered N-heterocyclic carbene ligand and initial studies of their use in asymmetric Wacker-type oxidative cyclization reactions. Tetrahedron. 2009;65:5084-5092.
Popp BV, Stahl SS. Mechanism of Pd(OAc)(2)/Pyridine Catalyst Reoxidation by O-2: Influence of Labile Monodentate Ligands and Identification of a Biomimetic Mechanism for O-2 Activation. Chemistry-A European Journal. 2009;15:2915-2922.
Mowery BP, Lindner AH, Weisblum B, Stahl SS, Gellman SH. Structure-activity Relationships among Random Nylon-3 Copolymers That Mimic Antibacterial Host-Defense Peptides. Journal of the American Chemical Society. 2009;131:9735-9745.
Lee M-R, Stahl SS, Gellman SH, Masters KS. Nylon-3 Copolymers that Generate Cell-Adhesive Surfaces Identified by Library Screening. Journal of the American Chemical Society. 2009;131:16779-16789.
King AE, Brunold TC, Stahl SS. Mechanistic Study of Copper-Catalyzed Aerobic Oxidative Coupling of Arylboronic Esters and Methanol: Insights into an Organometallic Oxidase Reaction. Journal of the American Chemical Society. 2009;131:5044-+.
Lee MR, Stahl SS, Gellman SH. Synthesis of beta-Lactams Bearing Functionalized Side Chains from a Readily Available Precursor. Organic Letters. 2008;10:5317-5319.
Huffman LM, Stahl SS. Carbon-nitrogen bond formation involving well-defined aryl-copper(III) complexes. Journal of the American Chemical Society. 2008;130:9196-+.
Hoerter JM, Otte KM, Gellman SH, Cui Q, Stahl SS. Discovery and mechanistic study of Al-III-catalyzed transamidation of tertiary amides. Journal of the American Chemical Society. 2008;130:647-654.
Hewgley BJ, Stahl SS, Kozlowski MC. Mechanistic study of asymmetric oxidative biaryl coupling: Evidence for self-processing of the copper catalyst to achieve control of oxidase vs oxygenase activity. Journal of the American Chemical Society. 2008;130:12232-+.
Hamada T, Ye X, Stahl SS. Copper-catalyzed aerobic oxidative amidation of terminal alkynes: Efficient synthesis of ynamides. Journal of the American Chemical Society. 2008;130:833-+.
Epand RF, Mowery BP, Lee SE, Stahl SS, Lehrer RI, Gellman SH, et al.. Dual mechanism of bacterial lethality for a cationic sequence-random copolymer that mimics host-defense antimicrobial peptides. Journal of Molecular Biology. 2008;379:38-50.
Konnick MM, Stahl SS. Reaction of molecular oxygen with a Pd-II-hydride to produce a Pd-II-hydroperoxide: Experimental evidence for an HX-reductive-elimination pathway. Journal of the American Chemical Society. 2008;130:5753-5762.
Popp BV, Wendlandt JE, Landis CR, Stahl SS. Reaction of molecular oxygen with an NHC-coordinated Pd-0 complex: Computational insights and experimental implications. Angewandte Chemie-International Edition. 2007;46:601-604.
Popp BV, Stahl SS. Insertion of Molecular Oxygen into a Palladium-Hydride Bond: Computational Evidence for Two Nearly Isoenergetic Pathways. Journal of the American Chemical Society. 2007;129:4410-4422.
Liu G, Stahl SS. Two-faced reactivity of alkenes: cis- versus trans-aminopalladation in aerobic pd-catalyzed intramolecular Aza-Wacker reactions. Journal of the American Chemical Society. 2007;129:6328-6335.
Kotov V, Scarborough CC, Stahl SS. Palladium-catalyzed aerobic oxidative amination of alkenes: Development of intra- and intermolecular Aza-Wacker reactions. Inorganic Chemistry. 2007;46:1910-1923.
Kissounko DA, Hoerter JM, Guzei IA, Cui Q, Gellman SH, Stahl SS. Ti-IV-mediated reactions between primary amines and secondary carboxamides: Amidine formation versus transamidation. Journal of the American Chemical Society. 2007;129:1776-1783.
Bell CM, Kissounko DA, Gellman SH, Stahl SS. Catalytic metathesis of simple secondary amides. Angewandte Chemie-International Edition. 2007;46:761-763.
Rogers MM, Kotov V, Chatwichien J, Stahl SS. Palladium-Catalyzed Oxidative Amination of Alkenes: Improved Catalyst Reoxidation Enables the Use of Alkene as the Limiting Reagent. Organic Letters. 2007;9:4331-4334.
Mowery BP, Lee SE, Kissounko DA, Epand RF, Epand RM, Weisblum B, et al.. Mimicry of antimicrobial host-defense peptides by random copolymers. Journal of the American Chemical Society. 2007;129:15474-15476.
Steinhoff BA, King AE, Stahl SS. Unexpected roles of molecular sieves in palladium-catalyzed aerobic alcohol oxidation. Journal of Organic Chemistry. 2006;71:1861-1868.
Popp BV, Stahl SS. "Oxidatively induced" reductive elimination of dioxygen from an eta(2-) peroxopalladium(II) complex promoted by electron-deficient alkenes. Journal of the American Chemical Society. 2006;128:2804-2805.
Hoerter JM, Otte KM, Gellman SH, Stahl SS. Mechanism of Al-III-catalyzed transamidation of unactivated secondary carboxamides. Journal of the American Chemical Society. 2006;128:5177-5183.
Steinhoff BA, Stahl SS. Mechanism of Pd(OAc)(2)/DMSO-catalyzed aerobic alcohol oxidation: Mass-transfer-limitation effects and catalyst decomposition pathways. Journal of the American Chemical Society. 2006;128:4348-4355.
Scarborough CC, Stahl SS. Synthesis of pyrrolidines via palladium(II)-catalyzed aerobic oxidative carboamination of butyl vinyl ether and styrenes with allyl tosylamides. Organic Letters. 2006;8:3251-3254.
Liu G, Stahl SS. Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation. Journal of the American Chemical Society. 2006;128:7179-7181.
Rogers MM, Wendlandt JE, Guzei IA, Stahl SS. Aerobic intramolecular oxidative amination of alkenes catalyzed by NHC-coordinated palladium complexes. Organic Letters. 2006;8:2257-2260.
Popp BV, Thorman JL, Stahl SS. Similarities between the reactions of dioxygen and alkenes with palladium(0): Relevance to the use of benzoquinone and molecular oxygen as stoichiometric oxidants in palladium-catalyzed oxidation reactions. Journal of Molecular Catalysis A. 2006;251:2-7.
Konnick MM, Gandhi BA, Guzei IA, Stahl SS. Reaction of molecular oxygen with a Pd-II-hydride to produce a Pd-II-hydroperoxide: Acid catalysis and implications for Pd-catalyzed aerobic oxidation reactions. Angewandte Chemie-International Edition. 2006;45:2904-2907.
Timokhin VI, Stahl SS. Bronsted base-modulated regioselectivity in the aerobic oxidative amination of styrene catalyzed by palladium. Journal of the American Chemical Society. 2005;127:17888-17893.
Scarborough CC, Popp BV, Guzei IA, Stahl SS. Development of 7-membered N-heterocyclic carbene ligands for transition metals. Journal of Organometallic Chemistry. 2005;690:6143-6155.
Brice JL, Harang JE, Timokhin VI, Anastasi NR, Stahl SS. Aerobic oxidative amination of unactivated alkenes catalyzed by palladium. Journal of the American Chemical Society. 2005;127:2868-2869.
Stahl SS. Palladium-catalyzed oxidation of organic chemicals with O-2. Science. 2005;309:1824-1826.
Scarborough CC, Grady MJW, Guzei IA, Gandhi BA, Bunel EE, Stahl SS. Pd-II complexes possessing a seven-membered N-heterocyclic carbene ligand. Angewandte Chemie-International Edition. 2005;44:5269-5272.
Kissounko DA, Guzei IA, Gellman SH, Stahl SS. Titanium(IV)-mediated conversion of carboxamides to amidines and implications for catalytic transamidation. Organometallics. 2005;24:5208-5210.
Eldred SE, Pancost MR, Otte KM, Rozema D, Stahl SS, Gellman SH. Effects of side chain configuration and backbone spacing on the gene delivery properties of lysine-derived cationic polymers. Bioconjugate Chemistry. 2005;16:694-699.
Steinhoff BA, Guzei IA, Stahl SS. Mechanistic characterization of aerobic alcohol oxidation catalyzed by Pd(OAc)(2)/pyridine including identification of the catalyst resting state and the origin of nonlinear [catalyst] dependence. Journal of the American Chemical Society. 2004;126:11268-11278.
Popp BV, Thorman JL, Morales CM, Landis CR, Stahl SS. "Inverse-electron-demand" ligand substitution: Experimental and computational insights into olefin exchange at palladium(0). Journal of the American Chemical Society. 2004;126:14832-14842.
Landis CR, Morales CM, Stahl SS. Insights into the Spin-Forbidden Reaction between L2Pd0 and Molecular Oxygen. Journal of the American Chemical Society. 2004;126:16302-16303.
Konnick MM, Guzei IA, Stahl SS. Characterization of peroxo and hydroperoxo intermediates in the aerobic oxidation of N-heterocyclic-carbene-coordinated palladium(0). Journal of the American Chemical Society. 2004;126:10212-10213.
Stahl SS. Palladium oxidase catalysis: Selective oxidation of organic chemicals by direct dioxygen-coupled turnover [Review]. Angewandte Chemie-International Edition. 2004;43:3400-3420.
Brice JL, Meerdink JE, Stahl SS. Formation of enamides via palladium(II)-catalyzed vinyl transfer from vinyl ethers to nitrogen nucleophiles. Organic Letters. 2004;6(11).
Stahl SS, Thorman JL, de Silva N, Guzei IA, Clark RW. "Inverse-electron-demand" ligand substitution in palladium(0)-olefin complexes. Journal of the American Chemical Society. 2003;125:12-13.
Eldred SE, Stone DA, Gellman SH, Stahl SS. Catalytic transamidation under moderate conditions. Journal of the American Chemical Society. 2003;125:3422-3423.
Timokhin VI, Anastasi NR, Stahl SS. Dioxygen-coupled oxidative amination of styrene. Journal of the American Chemical Society. 2003;125:12996-12997.
Steinhoff BA, Stahl SS. Ligand-modulated palladium oxidation catalysis: Mechanistic insights into aerobic alcohol oxidation with the Pd(OAc)(2)/pyridine catalyst system. Organic Letters. 2002;4:4179-4181.
Steinhoff BA, Fix SR, Stahl SS. Mechanistic study of alcohol oxidation by the Pd(OAc)(2)/O-2/DMSO catalyst system and implications for the development of improved aerobic oxidation catalysts. Journal of the American Chemical Society. 2002;124:766-767.
Drier TO, Stahl SS. The Wisconsin Schlenk Line: Incorporation of an Ergonomic Greaseless Three-Way Valve Design. Fusion: The Journal of the American Scientific Glassblowers Society. 2002;3:25-27.
Fix SR, Brice JL, Stahl SS. Efficient intramolecular oxidative amination of olefins through direct dioxygen-coupled palladium catalysis. Angewandte Chemie-International Edition. 2002;41:164-166.
Stahl SS, Thorman JL, Nelson RC, Kozee MA. Oxygenation of nitrogen-coordinated palladium(0): Synthetic, structural, and mechanistic studies and implications for aerobic oxidation catalysis. Journal of the American Chemical SocietyJournal of the American Chemical Society. 2001;123:7188-7189.
Stahl SS, Francisco WA, Merkx M, Klinman JP, Lippard SJ. Oxygen kinetic isotope effects in soluble methane monooxygenase. Journal of Biological Chemistry. 2001;276:4549-4553.
Valentine AM, Stahl SS, Lippard SJ. Mechanistic studies of the reaction of reduced methane monooxygenase hydroxylase with dioxygen and substrates. Journal of the American Chemical Society. 1999;121:3876-3887.
Blazyk JL, Brandstetter H, Frederick CA, Gassner GT, Kopp DA, Lippard SJ, et al.. The soluble methane monooxygenase: components and catalysis. Journal of Inorganic Biochemistry. 1999;74:37-37.
Stahl SS, Labinger JA, Bercaw JE. Homogeneous oxidation of alkanes by electrophilic late transition metals. Angewandte Chemie-International Edition. 1998;37:2181-2192.
Stahl SS, Labinger JA, Bercaw JE. Investigations of the factors affecting the stability of dihydrogen adducts of platinum(II). Inorganic Chemistry. 1998;37:2422-2431.
Wang L, Stahl SS, Labinger JA, Bercaw JE. (Alkyl)platinum(II) intermediates in C-H activation by platinum complexes in aqueous solution. Journal of Molecular Catalysis A-Chemical. 1997;116:269-275.
Stahl SS, Labinger JA, Bercaw JE. Exploring the mechanism of aqueous C-H activation by Pt(II) through model chemistry: Evidence for the intermediacy of alkylhydridoplatinum(IV) and alkane sigma-adducts. Journal of the American Chemical Society. 1996;118:5961-5976.
Luinstra GA, Wang L, Stahl SS, Labinger JA, Bercaw JE. C-H ACTIVATION BY AQUEOUS PLATINUM COMPLEXES - A MECHANISTIC STUDY. Journal of Organometallic Chemistry. 1995;504:75-91.
Luinstra GA, Wang L, Stahl SS, Labinger JA, Bercaw JE. OXIDATION OF ZEISES SALT BY PTCL6 2- - A MECHANISTIC MODEL FOR HYDROCARBON OXIDATION. Organometallics. 1994;13:755-756.