Department of Chemistry

College of Letters & Science
Schomaker JM. Interview with Jennifer M. Schomaker. Organic Chemistry Frontiers. 2020;7:442-444.
Nicastri KA, Schomaker JM. 1,2-Azide Migration Enables Synthesis of beta-Difluoroalkyl Azides. Chem. 2020;6:327-329.
Reeves RD, Kinkema CN, Landwehr EM, Vine LE, Schomaker JM. Stereodivergent Metal-Catalyzed Allene Cycloisomerizations. Synlett. 2020;31:627-631.
Huang MX, Paretsky J, Schomaker JM. Rigidifying Ag(I) Complexes for Selective Nitrene Transfer. Chemcatchem. 2020;.
Dequina HJ, Eshon J, Raskopf WT, Fernandez I, Schomaker JM. Rh-Catalyzed Aziridine Ring Expansions to Dehydropiperazines. 2020;22:3637-3641.
Eshon J, Nicastri KA, Schmid SC, Raskopf WT, Guzei IA, Fernandez I, et al.. Intermolecular 3+3 ring expansion of aziridines to dehydropiperi-dines through the intermediacy of aziridinium ylides. Nature Communications. 2020;11.
Schomaker JM, Vine LE, Zerull EE. Taming Nitrene Reactivity with Silver Catalysts. Synlett. 2020;.
Ju MS, Zerull EE, Roberts JM, Huang MX, Guzei IA, Schomaker JM. Silver-Catalyzed Enantioselective Propargylic C-H Bond Amination through Rational Ligand Design. 2020;142:12930-12936.
Liu L, Ward RM, Schomaker JM. Regioselective Intramolecular Allene Amidation Enabled by an EDA Complex. Chemistry-A European Journal. 2020;.
Corbin JR, Ketelboeter DR, Fernandez I, Schomaker JM. Biomimetic 2-Imino-Nazarov Cyclizations via Eneallene Aziridination. Journal of the American Chemical Society. 2020;142:5568-5573.
Scamp RJ, Scheffer B, Schomaker JM. Regioselective differentiation of vicinal methylene C-H bonds enabled by silver-catalysed nitrene transfer. Chemical Communications. 2019;55:7362-7365.
Ju M, Huang MX, Vine LE, Dehghany M, Roberts JM, Schomaker JM. Tunable catalyst-controlled syntheses of beta- and gamma-amino alcohols enabled by silver-catalysed nitrene transfer. Nature Catalysis. 2019;2:899-908.
Ju M, Guan WY, Schomaker JM, Harper KC. Sequential Reduction of Nitroalkanes Mediated by CS2 and Amidine/Guanidine Bases: A Controllable Nef Reaction. Organic Letters. 2019;21:8893-8898.
Gerstner NC, Schomaker JM. Stereocontrolled Synthesis of the Aminocyclopentitol Core of Jogyamycin via an Ichikawa Rearrangement Reaction. Journal of Organic Chemistry. 2019;84:14092-14100.
Liu L, Ward RM, Schomaker JM. Mechanistic Aspects and Synthetic Applications of Radical Additions to Allenes. Chemical Reviews. 2019;119:12422-12490.
Tansukawat ND, See AE, Jiranuntarat S, Corbin JR, Schomaker JM. Method for Small-Scale Production of Deuterochloroform. Journal of Organic Chemistry. 2018;83:8739-8742.
Eshon J, Foarta F, Landis CR, Schomaker JM. alpha-Tetrasubstituted Aldehydes through Electronic and Strain-Controlled Branch-Selective Stereoselective Hydroformylation. Journal of Organic Chemistry. 2018;83:10207-10220.
Schmid SC, Guzei IA, Fernandez I, Schomaker JM. Ring Expansion of Bicyclic Methyleneaziridines via Concerted, Near-Barrierless 2,3 -Stevens Rearrangements of Aziridinium Ylides. Acs Catalysis. 2018;8:7907-7914.
Alderson JM, Corbin JR, Schomaker JM. Investigation of transition metal-catalyzed nitrene transfer reactions in water. Bioorganic & Medicinal Chemistry. 2018;26:5270-5273.
Lani ASM, Schomaker JM. Site-Selective, Catalyst-Controlled Alkene Aziridination. Synthesis-Stuttgart. 2018;50:4462-4470.
Eshon J, Gerstner NC, Schomaker JM. Oxidative allene amination for the synthesis of nitrogen-containing heterocycles. Arkivoc. 2018;:204-233.
Weatherly C, Alderson JM, Berry JF, Hein JE, Schomaker JM. Catalyst-Controlled Nitrene Transfer by Tuning Metal:Ligand Ratios: Insight into the Mechanisms of Chemoselectivity. Organometallics. 2017;36:1649-1661.
Corbin JR, Schomaker JM. Tunable differentiation of tertiary C-H bonds in intramolecular transition metal-catalyzed nitrene transfer reactions. Chemical Communications. 2017;53:4346-4349.
Huang MX, Corbin JR, Dolan NS, Fry CG, Vinokur AI, Guzei IA, et al.. Synthesis, Characterization, and Variable-Temperature NMR Studies of Silver(I) Complexes for Selective Nitrene Transfer. Inorganic Chemistry. 2017;56:6725-6733.
Burke EG, Gold B, Hoang TT, Raines RT, Schomaker JM. Fine-Tuning Strain and Electronic Activation of Strain-Promoted 1,3-Dipolar Cycloadditions with Endocyclic Sulfamates in SNO-OCTs. Journal of the American Chemical Society. 2017;139:8029-8037.
Liu L, Gerstner NC, Oxtoby LJ, Guzei IA, Schomaker JM. Fluorinated Amine Stereotriads via Allene Amination. Organic Letters. 2017;19:3239-3242.
Alderson JM, Schomaker JM. Tandem Oxidative Derivatization of Nitrene Insertion Products for the Highly Diastereoselective Synthesis of 1,3-aminoalcohols. Chemistry-A European Journal. 2017;23:8571-8576.
Reeves RD, Phelps AM, Raimbach WAT, Schomaker JM. Diastereoselective Au-Catalyzed Allene Cycloisomerizations to Highly Substituted Cyclopentenes. Organic Letters. 2017;19:3394-3397.
Ju M, Weatherly CD, Guzei IA, Schomaker JM. Chemo- and Enantioselective Intramolecular Silver-Catalyzed Aziridinations. Angewandte Chemie-International Edition. 2017;56:9944-9948.
Burke EG, Schomaker JM. Synthetic Applications of Flexible SNO-OCT Strained Alkynes and Their Use in Postpolymerization Modifications. Journal of Organic Chemistry. 2017;82:9038-9046.
Schmid SC, Guzei IA, Schomaker JM. A Stereoselective 3+1 Ring Expansion for the Synthesis of Highly Substituted Methylene Azetidines. Angewandte Chemie-International Edition. 2017;56:12229-12233.
Alderson JM, Corbin JR, Schomaker JM. Tunable, Chemo- and Site-Selective Nitrene Transfer Reactions through the Rational Design of Silver(I) Catalysts. Accounts of Chemical Research. 2017;50:2147-2158.
Eshon J, Landis CR, Schomaker JM. Regioselective Rh-Catalyzed Hydroformylation of 1,1,3-Trisubstituted Allenes Using BisDiazaPhos Ligand. Journal of Organic Chemistry. 2017;82:9270-9278.
Vinokur AI, Yakovenko A, Liu L, Schomaker JM, Guzei IA. An Enantiotropic Disorder Partial Order Solid-State Transformation in a Molecular Solid Involving a Phase with Z'=12. Crystal Growth & Design. 2017;17:5984-5993.
Huang MX, Yang T, Paretsky JD, Berry JF, Schomaker JM. Inverting Steric Effects: Using "Attractive" Noncovalent Interactions To Direct Silver-Catalyzed Nitrene Transfer. Journal of the American Chemical Society. 2017;139:17376-17386.
Gerstner NC, Adams CS, Grigg RD, Tretbar M, Rigoli JW, Schomaker JM. Diastereoselective Synthesis of the Aminocyclitol Core of Jogyamycin via an Allene Aziridination Strategy. Organic Letters. 2016;18:284-287.
Phelps AM, Chan VS, Napolitano JG, Krabbe SW, Schomaker JM, Shekhar S. Ligand-Controlled Synthesis of Azoles via Ir-Catalyzed Reactions of Sulfoxonium Ylides with 2-Amino Heterocycles. Journal of Organic Chemistry. 2016;81:4158-4169.
Gerstner NC, Adams CS, Tretbar M, Schomaker JM. Stereocontrolled Syntheses of Seven-Membered Carbocycles by Tandem Allene Aziridination/[4+3] Reaction. Angewandte Chemie International Edition. 2016;55:13240-13243.
Touney EE, Van Hoveln R, Buttke CT, Freidberg MD, Guzei IA, Schomaker JM. Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes. Organometallics. 2016;35:3436-3439.
Scamp RJ, Jirak JG, Dolan NS, Guzei IA, Schomaker JM. A General Catalyst for Site-Selective C(sp(3))-H Bond Amination of Activated Secondary over Tertiary Alkyl C(sp(3))-H Bonds. Organic Letters. 2016;18:3014-3017.
Dolan NS, Scamp RJ, Yang T, Berry JF, Schomaker JM. Catalyst-Controlled and Tunable, Chemoselective Silver-Catalyzed Intermolecular Nitrene Transfer: Experimental and Computational Studies. Journal of the American Chemical Society. 2016;138:14658-14667.
Van Hoveln R, Hudson BM, Wedler HB, Bates DM, Le Gros G, Tantillo DJ, et al.. Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration. Journal of the American Chemical Society. 2015;137:5346-5354.
Schmid SC, Van Hoveln R, Rigoli JW, Schomaker JM. Development of N-Heterocyclic Carbene-Copper Complexes for 1,3-Halogen Migration. Organometallics. 2015;34:4164-4173.
Croisant MF, Van Hoveln R, Schomaker JM. Formal Dyotropic Rearrangements in Organometallic Transformations. European Journal of Organic Chemistry. 2015;:5897-5907.
Burke EG, Schomaker JM. Oxidative Allene Amination for the Synthesis of Azetidin-3-ones. Angewandte Chemie-International Edition. 2015;54:12097-12101.
Scamp RJ, Rigoli JW, Schomaker JM. Chemoselective silver-catalyzed nitrene insertion reactions. Pure and Applied Chemistry. IUPAC & De Gruyter; 2014;86:381-393.
Rigoli JW, Guzei IA, Schomaker JM. Aminodiols via Stereocontrolled Oxidation of Methyleneaziridines. Organic Letters. 2014;16:1696-1699.
Van Hoveln RJ, Schmid SC, Schomaker JM. 1,3-Halogen migration as an entry to aryl coppers from an unintuitive starting material. Organic & Biomolecular Chemistry. 2014;12:7655-7658.
Van Hoveln RJ, Schmid SC, Tretbar M, Buttke CT, Schomaker JM. Formal asymmetric hydrobromination of styrenes via copper-catalyzed 1,3-halogen migration. Chemical Science. 2014;5:4763-4767.
Adams CS, Weatherly CD, Burke EG, Schomaker JM. The conversion of allenes to strained three-membered heterocycles. Chemical Society Reviews. 2014;43:3136-3163.
Adams CS, Grigg RD, Schomaker JM. Complete stereodivergence in the synthesis of 2-amino-1,3-diols from allenes. Chemical Science. 2014;5:3046-3056.
Alderson JM, Phelps AM, Scamp RJ, Dolan NS, Schomaker JM. Ligand-Controlled, Tunable Silver-Catalyzed C-H Amination. Journal of the American Chemical Society. 2014;136:16720-16727.
Weatherly CD, Guzei IA, Schomaker JM. Stereocontrolled Synthesis of 1,3-Diamino-2-ols by Aminohydroxylation of Bicyclic Methylene-Aziridines. European Journal of Organic Chemistry. 2013;:3667-3670.
Schomaker JM, Grigg RD. Activating Group Recycling: A Fresh Approach to Arene Functionalization. Synlett. 2013;:401-407.
Rigoli JW, Weatherly CD, Vo BT, Neale S, Meis AR, Schomaker JM. Chemoselective Allene Aziridination via Ag(I) Catalysis. Organic Letters. 2013;15:290-293.
Phelps AM, Dolan NS, Connell NT, Schomaker JM. Divergent reactivity of allene-containing α-diazoesters using Cu and Rh catalysis. Tetrahedron. 2013;69:5614-5621.
Weatherly CD, Rigoli JW, Schomaker JM. Synthesis of 1,3-Diaminated Stereotriads via Rearrangement of 1,4-Diazaspiro 2.2 pentanes. Organic Letters. 2012;14:1704-1707.
Rigoli JW, Moyer SA, Pearce SD, Schomaker JM. alpha,beta-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines. Organic & Biomolecular Chemistry. 2012;10:1746-1749.
Grigg RD, Van Hoveln R, Schomaker JM. Copper-Catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration. Journal of the American Chemical Society. 2012;134:16131-16134.
Grigg RD, Rigoli JW, Van Hoveln R, Neale S, Schomaker JM. Beyond Benzyl Grignards: Facile Generation of Benzyl Carbanions from Styrenes. Chemistry-A European Journal. 2012;18:9391-9396.
Adams CS, Boralsky LA, Guzei IA, Schomaker JM. Modular Functionalization of Allenes to Aminated Stereotriads. Journal of the American Chemical Society. 2012;134:10807-10810.
Rigoli JW, Boralsky LA, Hershberger JC, Marston D, Meis AR, Guzei IA, et al.. 1,4-Diazaspiro[2.2]pentanes as a Flexible Platform for the Synthesis of Diamine-Bearing Stereotriads. Journal of Organic Chemistry. 2012;77:2446-2455.
Grigg DR, Rigoli JW, Pearce SD, Schomaker JM. Synthesis of Propargylic and Allenic Carbamates via the C-H Amination of Alkynes. Organic Letters. 2012;14:280-283.
Gladysz JA, Ball ZT, Bertrand G, Blum SA, Dong VM, Dorta R, et al.. Organometallics Roundtable 2011. Organometallics. 2012;31:1-18.
Guzei IA, Gunn EM, Spencer LC, Schomaker JM, Rigoli JW. Polymorphism of 5-(pyridin-2-ylmethylene)-3-phenyl-2-methylthio-3,5-dihydro-4H-imidazole -4-one. Crystengcomm. 2011;13:3444-3450.
Grigg DR, Schomaker JM, Timokhin V. C-H amination/cyclocarbonylation of allene carbamates: a versatile platform for the synthesis of alpha,beta-unsaturated gamma-lactams. Tetrahedron. 2011;67:4318-4326.
Boralsky LA, Marston D, Grigg DR, Hershberger JC, Schomaker JM. Allene Functionalization via Bicyclic Methylene Aziridines. Organic Letters. 2011;13:1924-1927.
Kulshrestha A, Schomaker JM, Holmes D, Staples RJ, Jackson JE, Borhan B. Selectivity in the Addition Reactions of Organometallic Reagents to Aziridine-2-carboxaldehydes: The Effects of Protecting Groups and Substitution Patterns. Chemistry-A European Journal. 2011;17:12326-12339, S12326/1-S12326/173.
Boyd CW, Crimmin MR, Rosebrugh LE, Schomaker JM, Bergman RG, Toste DF. Cobalt-Mediated, Enantioselective Synthesis of C-2 and C-1 Dienes. Journal of the American Chemical Society. 2010;132:16365-16367.
Schomaker JM, Toste FD, Bergman RG. Cobalt-Mediated [3+2]-Annulation Reaction of Alkenes with alpha,beta-Unsaturated Ketones and Imines. Organic Letters. 2009;11:3698-3700.
Schomaker JM, Boyd WC, Stewart IC, Toste FD, Bergman RG. Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins. Journal of the American Chemical Society. 2008;130:3777-+.
Schomaker JM, Borhan B. Total synthesis of haterumalides NA and NC via a chromium-mediated macrocyclization. Journal of the American Chemical Society. 2008;130:12228-+.
Schomaker JM, Geiser AR, Huang R, Borhan B. Tetrasubstituted pyrrolidines via a tandem aza-Payne/hydroamination reaction. Journal of the American Chemical Society. 2007;129:3794-+.
Schomaker JM, Bhattacharjee S, Yan J, Borhan B. Diastereomerically and enantiomerically pure 2,3-disubstituted pyrrolidines from 2,3-aziridin-1-ols using a sulfoxonium ylide: A one-carbon homologative relay ring expansion. Journal of the American Chemical Society. 2007;129:1996-2003.
Delia TJ, Schomaker JM, Kalinda AS. The synthesis of substituted phenylpyrimidines via Suzuki coupling reactions. Journal of Heterocyclic Chemistry. 2006;43:127-131.
Zheng T, Narayan RS, Schomaker JM, Borhan B. One-pot regio- and stereoselective cyclization of 1,2,n-triols. Journal of the American Chemical Society. 2005;127:6946-6947.
Schomaker JM, Pulgam VR, Borhan B. Synthesis of diastereomerically and enantiomerically pure 2,3-disubstituted tetrahydrofurans using a sulfoxonium ylide. Journal of the American Chemical Society. 2004;126:13600-13601.
Schomaker JM, Borhan B. Total synthesis of (+)-tanikolide via oxidative lactonization. Organic & Biomolecular Chemistry. 2004;2:621-624.
Delia TJ, Anderson DP, Schomaker JM. 2,4,6-trifluoropyrimidine. Reactions with nitrogen nucleophiles. Journal of Heterocyclic Chemistry. 2004;41:991-993.
Schomaker JM, Travis BR, Borhan B. Direct lactonization of alkenols via osmium tetroxide-mediated oxidative cleavage. Organic Letters. 2003;5:3089-3092.
Schomaker JM, Delia TJ. Arylation of halogenated pyrimidines via a Suzuki coupling reaction. Journal of Organic Chemistry. 2001;66:7125-7128.
Schomaker JM, Delia TJ. 2,4,6-trichloropyrimidine. Reaction with anilines. Journal of Heterocyclic Chemistry. 2000;37:1457-1462.
Delia TJ, Meltsner BR, Schomaker JM. 2,4,6-trichloropyrimidine. Reaction with sodium amide. Journal of Heterocyclic Chemistry. 1999;36:1259-1261.
Schomaker JM. Inside the Career of a Chemical Technician. American Careers. 1998;:6-7.